The Exciplex

Author: Gordon   M.  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780323152860

P-ISBN(Paperback): 9780122906503

P-ISBN(Hardback):  9780122906503

Subject: O6-0 chemical principle and method

Language: ENG

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Description

The Exciplex contains the proceedings of the International Exciplex Conference held at the University of Western Ontario, on May 28-31, 1974. The papers explore various aspects of exciplex behavior and cover topics ranging from singlet- and triplet-state exciplexes to the photophysics of aromatic excimers. Electron-transfer reactions in multicomponent systems are also considered, along with intramolecular triplet-state charge-transfer interactions in aminoketones.
Comprised of 15 chapters, this book opens with an overview of the photochemistry of excimers and exciplexes, followed by a discussion on singlet- and triplet-state exciplexes and the photophysics of aromatic excimers. Experimental results on intersystem crossing and ionic recombination processes are then presented, and electronic structures as well as dynamical behavior of some exciplex systems are described. The next chapters focus on excimers of hydrogen and acetone; complexes of dipolar excited states and small polar molecules; electron transfer and exciplex formation from triplet states of anthracene and metalloporphyrins; and exciplexes in electrogenerated chemiluminescence. The final chapter is devoted to intramolecular triplet-state charge-transfer interactions in aminoketones.
This monograph will be of interest to chemists and physicists.

Chapter

Front Cover

pp.:  1 – 4

The Exciplex

pp.:  4 – 5

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 8

CONTRIBUTORS

pp.:  8 – 10

PREFACE

pp.:  10 – 12

Dedication

pp.:  12 – 14

CHAPTER 2. SINGLET-AND TRIPLET-STATE EXCIPLEXES

pp.:  36 – 52

CHAPTER 3. THE PHOTOPHYSICS OF AROMATIC EXCIMERS

pp.:  52 – 88

CHAPTER 4. INTERSYSTEM CROSSING AND IONIC RECOMBINATION PROCESSES

pp.:  88 – 126

CHAPTER 5. ELECTRONIC STRUCTURES AND DYNAMICAL BEHAVIOR

pp.:  126 – 158

CHAPTER 6. HYDROGEN EXCIMER - A BOUND STATE OF H4

pp.:  158 – 178

CHAPTER 7. THE ACETONE EXCIMER. A CASE FOR THE CONCEPT OF "MASKED" OR "CRYPTO" ELECTRONICALLY EXCITED STATES

pp.:  178 – 200

CHAPTER 8. COMPLEXES OF DIPOLAR EXCITED STATES AND SMALL POLAR MOLECULES

pp.:  200 – 222

CHAPTER 9. CATION RADICAL INTERMEDIATES, EXCIPLEXES AND ENCOUNTER COMPLEXES IN PHOTOCHEMICALLY-INDUCED POLYMERIZATION AND CYCLODIMERIZATION OF OLEFINS

pp.:  222 – 260

CHAPTER 10. SPECTROSCOPIC STUDIES OF NONLUMINESCENT EXCIPLEXES. ELECTRON TRANSFER AND EXCIPLEX FORMATION FROM TRIPLET STATES OF ANTHRACENE AND METALLOPORPHYRINS

pp.:  260 – 288

CHAPTER 11. EXCIPLEXES IN CHEMILUMINESCENT RADICAL ION RECOMBINATION KLAAS ZACHARIASSE

pp.:  288 – 318

CHAPTER 12. EXCIPLEXES IN ELECTROGENERATED CHEMILUMINESCENCE

pp.:  318 – 340

CHAPTER 13. ELECTRON-TRANSFER REACTIONS IN MULTICOMPONENT SYSTEMS

pp.:  340 – 358

CHAPTER 14. SINGLET QUENCHING MECHANISMS - SENSITIZED DIMERIZATION OF PHENYL VINYL ETHER

pp.:  358 – 372

CHAPTER 15. INTRAMOLECULAR TRIPLET-STATE CHARGE-TRANSFER INTERACTIONS IN AMINOKETONES

pp.:  372 – 386

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