Thermodynamic Properties of Nonelectrolyte Solutions

Author: Acree   William  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780323140676

P-ISBN(Paperback): 9780120430208

P-ISBN(Hardback):  9780120430208

Subject: O645.16 Solution Properties

Language: ENG

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Description

Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics.
This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures.
This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 10

Preface

pp.:  10 – 12

Chapter 2. Partial Molar Quantities

pp.:  23 – 41

Chapter 3. Ideal and Nonideal Solutions

pp.:  41 – 73

Chapter 4. Empirical Expressions for Estimating Multicomponent Properties from Binary Data

pp.:  73 – 85

Chapter 5. Binary and Ternary Mixtures Containing Only Nonspecific Interactions

pp.:  85 – 126

Chapter 6. Prediction of Thermodynamic Excess Properties of Liquid Mixtures Based on Group Contribution Methods

pp.:  126 – 145

Chapter 7. Simple Associated Solutions

pp.:  145 – 161

Chapter 8. Estimation of Thermodynamic Excess Properties of Ternary-Alcohol Hydrocarbon Systems from Binary Data

pp.:  161 – 187

Chapter 9. Vapor–Liquid Equilibrium and Azeotropic Systems

pp.:  187 – 208

Chapter 10. Solubility Behavior of Nonelectrolytes

pp.:  208 – 251

Chapter 11. Liquid–Liquid Equilibrium: Distribution of a Solute between Two Immiscible Liquid Phases

pp.:  251 – 268

Chapter 12. Physio-Chemical Applications of Gas–Liquid Chromatography to Nonelectrolyte Solutions

pp.:  268 – 282

Appendix A: Solubility Parameters and Molar Volumes at 25°C

pp.:  282 – 285

Appendix B: UNIQUAC Structural Parameters

pp.:  285 – 286

Appendix C: Constants and Conversion Factors

pp.:  286 – 287

Appendix D: Answers to Selected Problems

pp.:  287 – 298

References

pp.:  298 – 306

Index

pp.:  306 – 320

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