Privileged Chiral Ligands and Catalysts

Author: Qi-Lin Zhou  

Publisher: John Wiley & Sons Inc‎

Publication year: 2011

E-ISBN: 9783527635221

P-ISBN(Hardback):  9783527327041

Subject: O643.3 catalytic

Language: ENG

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Description

Catalytic asymmetric synthesis has been one of the most active research areas in chemistry (Nobel Prize in 2001). The development of efficient chiral catalysts plays a crucial role in asymmetric catalysis. Although many chiral ligands/catalysts have been developed in the past decades, the most efficient catalysts are derived from a few core structures, called "privileged chiral catalysts". This ultimate "must have" and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these "privileged catalysts". This novel presentation provides readers with a much deeper insight into the topic and makes it a must-have for organic chemists, catalytic chemists, chemists working with/on organometallics, chemists in industry, and libraries.

From the contents:
* BINAP
* Bisphosphacycles - From DuPhos and BPE to a Diverse Set of Broadly Applied Ligands
* Josiphos Ligands: From Discovery to Technical Applications
* Chiral Spiro Ligands
* Chiral Bisoxazoline Ligands
* PHOX Ligands
* Chiral Salen Complexes
* BINOL
* TADDOLate Ligands
* Cinchona Alkaloids
* Proline Derivatives

Chapter

Contents

pp.:  5 – 7

Preface

pp.:  7 – 17

List of Contributors

pp.:  17 – 21

3: Josiphos Ligands: From Discovery to Technical Applications: Hans-Ulrich Blaser, Benoît Pugin, Felix Spindler, Esteban Mejía, and Antonio Togni

pp.:  79 – 117

4: Chiral Spiro Ligands: Shou-Fei Zhu and Qi-Lin Zhou

pp.:  117 – 161

5: Chiral Bisoxazoline Ligands: Levi M. Stanley and Mukund P. Sibi

pp.:  161 – 195

6: PHOX Ligands: Cory C. Bausch and Andreas Pfaltz

pp.:  195 – 245

7: Chiral Salen Complexes: Wen-Zhen Zhang and Xiao-Bing Lu

pp.:  245 – 281

8: BINOL: Masakatsu Shibasaki and Shigeki Matsunaga

pp.:  281 – 319

9: TADDOLate Ligands: Hélène Pellissier

pp.:  319 – 357

10: Cinchona Alkaloids: Hongming Li, Yonggang Chen and Deng Li

pp.:  357 – 385

11: Proline Derivatives: Shilei Zhang and Wei Wang

pp.:  385 – 433

Index

pp.:  433 – 471

LastPages

pp.:  471 – 487

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