Fragments of Fullerenes and Carbon Nanotubes :Designed Synthesis, Unusual Reactions, and Coordination Chemistry

Publication subTitle :Designed Synthesis, Unusual Reactions, and Coordination Chemistry

Author: Marina A. Petrukhina  

Publisher: John Wiley & Sons Inc‎

Publication year: 2011

E-ISBN: 9781118011225

P-ISBN(Hardback):  9780470569085

Subject: O613.71 Carbon C

Language: ENG

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Description

This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions.   The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials.  It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.

Chapter

CONTENTS

pp.:  1 – 7

PREFACE

pp.:  7 – 9

FOREWORD

pp.:  9 – 13

CONTRIBUTORS

pp.:  13 – 15

ACRONYMS

pp.:  15 – 19

3 ANIONS OF BUCKYBOWLS

pp.:  61 – 83

4 CURVED π-CONJUGATED STABLE OPEN-SHELL SYSTEMS POSSESSING THREE-DIMENSIONAL MOLECULAR/ELECTRONIC SPIN STRUCTURES

pp.:  83 – 115

5 EXPERIMENTAL AND CALCULATED PROPERTIES OF FULLERENE AND NANOTUBE FRAGMENTS

pp.:  115 – 155

6 COORDINATION PREFERENCES OF BOWL-SHAPED POLYAROMATIC HYDROCARBONS

pp.:  155 – 177

7 SUMANENES: SYNTHESIS AND COMPLEXATION

pp.:  177 – 207

8 σ-BONDED TRANSITION METAL COMPLEXES OF POLYCYCLIC AROMATIC CARBON COMPOUNDS

pp.:  207 – 225

9 HEMISPHERICAL GEODESIC POLYARENES: ATTRACTIVE TEMPLATES FOR THE CHEMICAL SYNTHESIS OF UNIFORM-DIAMETER ARMCHAIR NANOTUBES

pp.:  225 – 255

10 AROMATIC BELTS AS SECTIONS OF NANOTUBES

pp.:  255 – 279

11 CYCLOPARAPHENYLENES: THE SHORTEST POSSIBLE SEGMENTS OF ARMCHAIR CARBON NANOTUBES

pp.:  279 – 311

12 CONJUGATED MOLECULAR BELTS BASED ON 3D BENZANNULENE SYSTEMS

pp.:  311 – 331

13 TOWARD FULLY UNSATURATED DOUBLE-STRANDED CYCLES

pp.:  331 – 363

14 BENT PYRENES: SPRINGBOARDS TO AROMATIC BELTS?

pp.:  363 – 387

INDEX

pp.:  387 – 421

LastPages

pp.:  421 – 433

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