Spatial-Energy Principles of the Processes for Complex Structure Formation

Author: G. A. Korablev  

Publisher: De Gruyter‎

Publication year: 2005

E-ISBN: 9783110935035

P-ISBN(Paperback): 9789067644235

Subject: O64 (physical chemistry) and theoretical chemistry, chemical physics

Language: ENG

Access to resources Favorite

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Chapter

Preface

pp.:  1 – 11

Introduction

pp.:  11 – 14

2.4. Calculations of electron density inside an atom via P-parameter and principle of adding reverse values of P-parameters

pp.:  48 – 52

2.5. Dependence of P-parameter upon the modulus of maximum values of Y-function radial part

pp.:  52 – 55

2.6. Dependence of spectral characteristics of atoms upon their spatial-energy parameters

pp.:  55 – 58

2.7. Wave equation of P-parameter

pp.:  58 – 59

2.8. Wave properties of P-parameter and addition principles of P-parameters

pp.:  59 – 63

2.9. Some additive properties of P-parameter

pp.:  63 – 66

2.10. P-parameter as an objective characteristics of electronegativity

pp.:  66 – 67

Chapter 3. Experimental evidence of spatial-energy criterion of isomorphism and solubility

pp.:  67 – 71

3.1. Elementary systems of M’ - M” type

pp.:  71 – 71

3.2. Estimation of isomorphic replacements in complex systems

pp.:  71 – 89

3.4. Morphology of state diagrams of quasi-binary systems of vanadates of metals of II group

pp.:  89 – 96

3.3. Experimental check of P-parameter application taking atom coordination into account

pp.:  89 – 89

3.5. Application of effective PE-parameter

pp.:  96 – 102

Chapter 4. Temperature characteristics of solid solution expansion with the help of Pparameter (at given temperature)

pp.:  102 – 123

4.1. Estimation of mutual solubility of binary system components

pp.:  123 – 125

4.2. Systems of M’0 - M”0 type

pp.:  125 – 142

4.3. Phase-formation and thermal properties in systems A12O3-M2O3

pp.:  142 – 147

4.4. Estimation of carbon solubility in metals for refractory compounds at given temperature

pp.:  147 – 151

4.5. Calculations of oxygen solubility in metals

pp.:  151 – 154

4.6. Method experimental check; directed search of inorganic materials

pp.:  154 – 163

Chapter 5. Spatial-energy criterion of compound formation

pp.:  163 – 173

5.2. Crystals with basic ionic bond

pp.:  173 – 176

5.1. P-parameter as a basic criterion of stable phase formation

pp.:  173 – 173

5.3. Crystals with ionic-covaience and metallic bonds. Intermetallides

pp.:  176 – 179

5.4. Crystalline penetration structures

pp.:  179 – 185

5.5. Estimation of ultimate carbon content value in carbide systems MCl-x

pp.:  185 – 189

Chapter 6. Other applications of P-parameter in inorganic chemistry and chemistry of solids

pp.:  189 – 196

6.2. Shift modulus determination for metals and carbide compounds

pp.:  196 – 204

6.1. Calculations of effective ionization sections of atoms and molecules at electron shock

pp.:  196 – 196

6.3. Calculations of activation energy of volume diffusion and self-diffusion in solids

pp.:  204 – 209

6.4. Estimation of alloy amorphization possibility

pp.:  209 – 219

6.5. Solubility of components of solid solutions of system W-Co-C-O-N

pp.:  219 – 227

6.6. Estimation of cluster-formation in system CaSO4-H2O

pp.:  227 – 232

Chapter 7. Kinetics and phase-formation in fast physic-chemical processes

pp.:  232 – 239

7.1. Methods for calculating P-parameters of complex organic compounds

pp.:  239 – 239

7.2. Dependence of activation energy of chemical reactions upon spatial-energy characteristics of atoms

pp.:  239 – 242

7.3. Basic structural interactions of components in systems OCTOGEN (OG) – nitroglycerine (NG)

pp.:  242 – 245

7.4. Phase-formation features of polymeric composite (PC) components

pp.:  245 – 261

Conclusion

pp.:  261 – 270

General conclusions

pp.:  270 – 274

References

pp.:  274 – 276

Appendix I. P-parameter additive properties

pp.:  276 – 306

Appendix II. Isomorphism of elementary systems

pp.:  306 – 319

Appendix III. PO-parameters of valence orbitals of neutral atoms in basic state (calculated via atom ionization energy)

pp.:  319 – 378

Appendix IV. P-parameters of some atoms calculated via electron bond energy according to Fischer

pp.:  378 – 388

Appendix V. Calculations of P0-parameters of some atoms using electron bond energy by ESCA

pp.:  388 – 409

Appendix VI. Calculations of errors when estimating solubility of components using Parameter method

pp.:  409 – 411

Appendix VII. Methods of experiments conducted for determining the solubility boundaries of complex system components

pp.:  411 – 419

Appendix VIII. Analog comparisons of Lagrangian and Hamilton functions with spatial-energy parameter

pp.:  419 – 423

LastPages

pp.:  423 – 433

The users who browse this book also browse


No browse record.