Modern Methods for the Determination of Non-Metals in Non-Ferrous Metals :Applications to Particular Systems of Metallurgical Importance

Publication subTitle :Applications to Particular Systems of Metallurgical Importance

Author: C. Engelmann   Günther Kraft   J. Pauwels   C. Vandecasteele  

Publisher: De Gruyter‎

Publication year: 1985

E-ISBN: 9783110862447

P-ISBN(Paperback): 9783110103427

Subject: O613 non - metalic compound

Language: ENG

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Chapter

2. Oxygen

pp.:  15 – 15

1. Introduction

pp.:  15 – 15

2.2 Oxygen in aluminium

pp.:  15 – 17

2.1 Oxygen in copper

pp.:  15 – 15

2.3 Oxygen in lead

pp.:  17 – 19

2.4 Oxygen in titanium

pp.:  19 – 19

2.5 Oxygen in zirconium

pp.:  19 – 21

3. Nitrogen

pp.:  23 – 24

3.2 Nitrogen in niobium

pp.:  24 – 25

3.3 Nitrogen in tantalum

pp.:  25 – 26

3.4 Nitrogen in molybdenum

pp.:  26 – 27

3.5 Nitrogen in tungsten

pp.:  27 – 28

4.2 Carbon in copper

pp.:  28 – 29

4.1 Carbon in aluminium

pp.:  28 – 28

4. Carbon

pp.:  28 – 28

4.6 Carbon in niobium

pp.:  29 – 30

4.5 Carbon in zirconium

pp.:  29 – 29

4.4 Carbon in titanium

pp.:  29 – 29

4.3 Carbon in nickel

pp.:  29 – 29

4.9 Carbon in tungsten

pp.:  30 – 31

4.7 Carbon in tantalum

pp.:  30 – 30

4.8 Carbon in molybdenum

pp.:  30 – 30

6. Sulphur

pp.:  31 – 32

5. Boron

pp.:  31 – 31

8. References

pp.:  32 – 33

7. Phosphorus

pp.:  32 – 32

6.2 Sulphur in nickel

pp.:  32 – 32

6.1 Sulphur in copper

pp.:  32 – 32

1.1 Introduction

pp.:  34 – 34

1. Neutron activation analysis

pp.:  34 – 34

2.1 Nuclear reactions

pp.:  39 – 39

2.2 Stopping power and range

pp.:  39 – 42

2.3 Standardization

pp.:  42 – 45

2.4 Samples and standards

pp.:  45 – 62

2.5 Irradiation

pp.:  62 – 63

2.6 Influence of radionuclides formed at the surface

pp.:  63 – 69

2.7 Chemical separation of the radionuclides produced

pp.:  69 – 79

2.9 Calculations

pp.:  79 – 81

2.8 Determination of the induced activity

pp.:  79 – 79

3. Photon activation analysis

pp.:  81 – 82

3.2 Gamma photon generators

pp.:  82 – 84

3.1 Introduction

pp.:  82 – 82

3.3 Standardization

pp.:  84 – 86

3.4 Nuclear reactions

pp.:  86 – 88

3.5 Nuclear interferences

pp.:  88 – 88

3.6 Theoretical possibilities

pp.:  88 – 91

3.7 Irradiation facilities

pp.:  91 – 93

3.8 Radiochemical separation

pp.:  93 – 97

3.9 Specific advantages of the method

pp.:  97 – 107

4. References

pp.:  107 – 108

Chapter III: SAMPLE PREPARATION AND SURFACE ANALYSIS

pp.:  108 – 115

2. Measurement of surface concentrations

pp.:  115 – 119

1. Introduction

pp.:  115 – 115

2.1 Principle of the method

pp.:  119 – 119

2.2 Nuclear reactions

pp.:  119 – 122

2.3 Standardization

pp.:  122 – 123

2.4 Comment

pp.:  123 – 124

3.2 Final shaping of the sample

pp.:  124 – 125

3.1 Rough preparation of the analytical sample

pp.:  124 – 124

3. Mechanical shaping of analysis samples

pp.:  124 – 124

4. Shaping of large series of samples

pp.:  125 – 127

5. Chemical etching

pp.:  127 – 131

6. Recommended procedures

pp.:  131 – 132

6.2 Aluminium-silicon alloys

pp.:  132 – 133

6.1 Primary ingot aluminium

pp.:  132 – 132

6.3 Aluminium-magnesium alloys

pp.:  133 – 133

6.4 Copper

pp.:  133 – 134

6.6 Lead and lead alloys

pp.:  134 – 134

6.5 Brass

pp.:  134 – 134

6.7 Nickel

pp.:  134 – 136

6.8 Titanium and TiAl6V4-alloy

pp.:  136 – 137

6.10 Molybdenum

pp.:  137 – 138

6.9 Zirconium

pp.:  137 – 137

6.12 Niobium

pp.:  138 – 139

6.11 Tungsten

pp.:  138 – 138

7. References

pp.:  139 – 140

6.13 Tantalum

pp.:  139 – 139

Chapter IV: THE DETERMINATION OF BORON

pp.:  140 – 143

1.2 The determination of boron in zirconium and zircaloy

pp.:  143 – 151

1.1 The determination of boron in aluminium

pp.:  143 – 143

1. Chemical methods

pp.:  143 – 143

2. Charged particle activation analysis

pp.:  151 – 157

2.1 Nuclear reactions

pp.:  157 – 157

2.2 Standards

pp.:  157 – 161

2.3 The determination of boron in aluminium and aluminium-magnesium alloys

pp.:  161 – 162

2.4 The determination of boron in zirconium and zircaloy

pp.:  162 – 163

3. Evaluation of methods

pp.:  163 – 172

3.2 The determination of boron in aluminium-magnesium alloys

pp.:  172 – 174

3.1 The determination of boron in aluminium

pp.:  172 – 172

3.3 The determination of boron in zirconium and zircaloy

pp.:  174 – 175

4. References

pp.:  175 – 178

Chapter V: THE DETERMINATION OF CARBON

pp.:  178 – 181

1. Chemical methods

pp.:  181 – 181

1.2 The determination of carbon in aluminium

pp.:  181 – 182

1.1 Introduction

pp.:  181 – 181

1.3 The determination of carbon in titanium, zirconium and zircaloy

pp.:  182 – 184

1.4 The determination of carbon in niobium, tantalum, molybdenum and tungsten

pp.:  184 – 189

1.5 The determination of carbon in copper

pp.:  189 – 193

1.6 The determination of carbon in nickel

pp.:  193 – 194

2. Charged particle activation analysis

pp.:  194 – 195

2.1 Nuclear reactions

pp.:  195 – 195

2.2 The determination of carbon in aluminium

pp.:  195 – 195

2.3 The determination of carbon in nickel

pp.:  195 – 197

2.4 The determination of carbon in zirconium and zircaloy

pp.:  197 – 197

2.5 The determination of carbon in niobium and tantalum

pp.:  197 – 199

2.6 The determination of carbon in molybdenum and tungsten

pp.:  199 – 200

3. Photon activation analysis

pp.:  200 – 201

3.2 The determination of carbon in aluminium

pp.:  201 – 203

3.1 The determination of carbon in sodium

pp.:  201 – 201

3.3 The determination of carbon in nickel

pp.:  203 – 204

3.5 Other examples of carbon determinations in non-ferrous metals

pp.:  204 – 208

3.4 The determination of carbon in refractory metals

pp.:  204 – 204

4. Evaluation of methods

pp.:  208 – 209

4.2 The determination of carbon in zirconium and zircaloy

pp.:  209 – 211

4.1 The determination of carbon in aluminium

pp.:  209 – 209

4.3 The determination of carbon in molybdenum and tungsten

pp.:  211 – 212

5. References

pp.:  212 – 214

Chapter VI: THE DETERMINATION OF NITROGEN

pp.:  214 – 220

1.1 The determination of nitrogen in zirconium and its alloys

pp.:  220 – 220

1.2 The determination of nitrogen in titanium and its alloys

pp.:  220 – 227

1. Chemical methods

pp.:  220 – 220

1.3 The determination of nitrogen in niobium and tantalum

pp.:  227 – 230

1.4 The determination of nitrogen in molybdenum and tungsten

pp.:  230 – 243

1.5 The determination of nitrogen in nickel

pp.:  243 – 245

2. Charged particle activation analysis

pp.:  245 – 246

2.3 The determination of nitrogen in titanium and its alloys

pp.:  246 – 248

2.1 Introduction

pp.:  246 – 246

2.2 Nuclear reactions

pp.:  246 – 246

2.4 The determination of nitrogen in nickel

pp.:  248 – 250

2.5 The determination of nitrogen in zirconium and zircaloy

pp.:  250 – 251

2.6 The determination of nitrogen in niobium and tantalum

pp.:  251 – 255

2.7 The determination of nitrogen in molybdenum and tungsten

pp.:  255 – 258

3. Proton activation analysis

pp.:  258 – 259

3.2 The determination of nitrogen in aluminium

pp.:  259 – 260

3.1 The determination of nitrogen in sodium

pp.:  259 – 259

3.3 The determination of nitrogen in nickel

pp.:  260 – 260

3.4 The determination of nitrogen in refractory metals

pp.:  260 – 262

3.5 Other examples of nitrogen determinations in non-ferrous metals

pp.:  262 – 263

4. Evaluation of methods

pp.:  263 – 263

4.1 The determination of nitrogen in zirconium and zircaloy

pp.:  263 – 263

4.2 The determination of nitrogen in titanium and TiAl6V4-alloy

pp.:  263 – 265

4.3 The determination of nitrogen in molybdenum and tungsten

pp.:  265 – 266

4.4 The determination of nitrogen in nickel

pp.:  266 – 267

5. References

pp.:  267 – 268

Chapter VII: THE DETERMINATION OF OXYGEN

pp.:  268 – 273

1.2 The determination of oxygen in aluminium alloys

pp.:  273 – 280

1.1 The determination of oxygen in aluminium

pp.:  273 – 273

1. Chemical methods

pp.:  273 – 273

1.3 The determination of oxygen in copper

pp.:  280 – 281

1.4 The determination of oxygen in copper alloys

pp.:  281 – 294

1.5 The determination of oxygen in lead

pp.:  294 – 301

1.6 The determination of oxygen in lead alloys

pp.:  301 – 304

1.7 The determination of oxygen in nickel

pp.:  304 – 304

1.8 The determination of oxygen in zirconium, titanium and their alloys

pp.:  304 – 305

1.9 The determination of oxygen in niobium and tantalum

pp.:  305 – 313

1.10 The determination of oxygen in molybdenum

pp.:  313 – 317

1.11 The determination of oxygen in tungsten

pp.:  317 – 320

2. 14 MeV neutron activation analysis

pp.:  320 – 321

2.3 Irradiation and measuring conditions

pp.:  321 – 322

2.1 Nuclear reactions

pp.:  321 – 321

2.2 Apparatus

pp.:  321 – 321

2.4 Samples, standards and flux monitors

pp.:  322 – 323

2.5 Sources of errors

pp.:  323 – 324

2.6 Precision and sensitivity

pp.:  324 – 329

2.7 Results

pp.:  329 – 332

3.1 Nuclear reactions

pp.:  332 – 332

3.2 The chemical separation of 18F

pp.:  332 – 334

3. Charged particle activation analysis

pp.:  332 – 332

3.3 The determination of oxygen in aluminium

pp.:  334 – 338

3.4 The determination of oxygen in titanium, zirconium and their alloys

pp.:  338 – 341

3.5 The determination of oxygen in nickel

pp.:  341 – 342

3.6 The determination of oxygen in copper

pp.:  342 – 343

3.7 The determination of oxygen in molybdenum and tungsten

pp.:  343 – 345

3.8 The determination of oxygen in tantalum

pp.:  345 – 347

4. Photon activation analysis

pp.:  347 – 348

3.9 The determination of oxygen in lead

pp.:  347 – 347

4.1 The determination of oxygen in sodium

pp.:  348 – 348

4.2 The determination of oxygen in aluminium

pp.:  348 – 349

4.3 The determination of oxygen in nickel and copper

pp.:  349 – 350

4.5 The determination of oxygen in lead and its alloys

pp.:  350 – 355

4.4 The determination of oxygen in refractory metals

pp.:  350 – 350

4.6 Other examples of oxygen determinations in non-ferrous metals

pp.:  355 – 356

5. Evaluation of methods

pp.:  356 – 357

5.1 The determination of oxygen in aluminium

pp.:  357 – 357

5.2 The determination of oxygen in copper

pp.:  357 – 359

5.3 The determination of oxygen in lead and its alloys

pp.:  359 – 360

5.4 The determination of oxygen in nickel

pp.:  360 – 361

5.5 The determination of oxygen in titanium, zirconium and their alloys

pp.:  361 – 362

5.6 The determination of oxygen in niobium and tantalum

pp.:  362 – 362

5.7 The determination of oxygen in molybdenum

pp.:  362 – 364

5.8 The determination of oxygen in tungsten

pp.:  364 – 365

Chapter VIII: THE DETERMINATION OF PHOSPHORUS

pp.:  365 – 380

6. References

pp.:  365 – 365

1. Chemical methods

pp.:  380 – 380

2. Charged particle activation analysis

pp.:  380 – 386

2.3 Results and discussion

pp.:  386 – 389

2.1 Nuclear reactions

pp.:  386 – 386

2.2 Experimental procedure for the determination of phosphorus in aluminium alloys

pp.:  386 – 386

3. Neutron activation analysis

pp.:  389 – 390

3.2 Applications

pp.:  390 – 390

3.3 The determination of phosphorus in aluminium-silicon alloy

pp.:  390 – 391

3.1 Nuclear reactions

pp.:  390 – 390

3.4 The determination of phosphorus (and sulphur) in copper and nickel

pp.:  391 – 392

4. Evaluation of methods

pp.:  392 – 394

5. References

pp.:  394 – 394

Chapter IX: THE DETERMINATION OF SULPHUR

pp.:  394 – 396

1. Chemical methods

pp.:  396 – 396

1.2 The determination of sulphur in nickel

pp.:  396 – 406

1.1 The determination of sulphur in copper

pp.:  396 – 396

2. Charged particle activation analysis

pp.:  406 – 408

2.1 Nuclear reactions

pp.:  408 – 408

2.2 Experimental procedure for the determination of sulphur in copper and nickel

pp.:  408 – 409

2.3 Results and discussion

pp.:  409 – 411

3. Neutron activation analysis

pp.:  411 – 412

3.2 Applications

pp.:  412 – 413

3.1 Nuclear reactions

pp.:  412 – 412

5. References

pp.:  413 – 413

Appendix

pp.:  413 – 415

4. Evaluation of methods

pp.:  413 – 413

LastPages

pp.:  415 – 425

Subject index

pp.:  415 – 415

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