Extraction of Rhodamine 6G Dye from Liquid Waste Solution: Study on Emulsion Liquid Membrane Stability Performance and Recovery

Author: Othman Norasikin   Yi Ooi Zing   Zailani Siti Nazrah   Zulkifli Erni Zuliana   Subramaniam Shanti  

Publisher: Taylor & Francis Ltd

ISSN: 0149-6395

Source: Separation Science and Technology, Vol.48, Iss.8, 2013-04, pp. : 1177-1183

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Effluent from industry using coloring material is hazardous to the environment because it is toxic in nature. Thus, it is important to treat the effluent to preserve the environment. In this research, extraction of Rhodamine 6G (R6G) from liquid wastewater using emulsion liquid membrane (ELM) process was studied. ELM formulation consists of kerosene as diluent, bis (2-ethylhexyl) phosphate (D2EHPA) as carrier, sulphuric acid (H2SO4) as internal phase, and SPAN 80 as surfactant. Several parameters had been examined to determine the stability of ELM and the recovery of R6G basic dyes from liquid waste solutions. The results show that the most stable emulsion was obtained with formulation consists of 0.1 M D2EHPA, 1.0 M of H2SO4 by using 12000 rpm homogenizer speed at 5 minutes emulsifying time. Furthermore, the result of recovery R6G in ELM process shows that the optimum condition of 50 ppm concentration of dye extraction were 5 minutes extraction time with the concentration of Span 80 at 3% w/v, agitation speed at 150 rpm, and the condition of 1:3 treat ratio. At this condition, the percentage of extraction and recovery were 100% and 84% respectively. Hence, the conclusion that ELM is a very promising technique for separating R6G from liquid wastewater.