Author： Abrahams A. Gerber T. I. A. Mayer P.
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.58, Iss.15, 2005-10, pp. : 1387-1393
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
Complexes of general formula [ReOX2{(C5H4N)CH(O)CH2(C5H4N)}] (X=Cl,I) were prepared by reaction of trans -[ReOCl3(PPh3)2] and trans -[ReOI2(OEt)(PPh3)2] with cis -1,2-di-(2-pyridyl)ethylene (DPE) in ethanol and benzene in air. The coordinated DPE ligand undergoes addition of water at the ethylenic carbon atoms, and the (C5H4N)CH(O)CH2(C5H4N) moiety acts as a uninegative terdentate N,O,N-donor ligand. X-ray crystal structures of both complexes have been determined and show distorted octahedral geometry at the rhenium(V) centre.
Related content
2,2′-dipyridylamine complexes of rhenium(V)
By Gerber T.I.A. Abrahams A. Mayer P. Hosten E.
Journal of Coordination Chemistry, Vol. 56, Iss. 16, 2003-11 ,pp. :
Access to resources
Recommend
By Booysen Irvin Gerber Thomas Hosten Eric Luzipo Dibanisile Mayer Peter
Journal of Coordination Chemistry, Vol. 60, Iss. 6, 2007-01 ,pp. :