Author： Ji Yong Xu Ming Liu Wei Fun Hoong-Kun Zuo Jing-Lin You Xiao-Zeng
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.58, Iss.17, 2005-11, pp. : 1573-1579
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Abstract
A series of new complexes of multi-sulfur 1,2-dithiolene ligands, [Ru(bipy) 3 ][Ni(L) 2 ] 2 (bipy?=?2,2'-bipyridine; L?=?pddt (6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate), dddt (5,6-dihydro-1,4-dithiin-2,3-dithiolate)), have been synthesized and characterized. One typical complex, [Ru(bipy) 3 ][Ni(pddt) 2 ] 2 ·2H 2 O (1), crystallized in an acentric space group of P 2 1 2 1 2 1 , with the cell dimensions of a ?=?8.634(1), b ?=?14.560(1), c ?=?49.889(5)?Å, a?=?ß?=???=?90°, and Z ?=?4. It consists of alternating columns of cations and anions along the a direction. The structure was refined by full matrix least squares methods to R 1 ?=?0.0340, wR 2 ?=?0.0670. Magnetic studies on [Ph 2 Cr][Ni(dddt) 2 ] are also reported.
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