Author： Bo Liu Hong Zhou Zhi-Quan Pan You Song Cheng-Gang Wang Han-Ping Zhang Jing-Dong Hu Ru-An Chi
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.59, Iss.11, 2006-07, pp. : 1271-1280
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Abstract
A macrocyclic heterodinuclear complex [Cu(II)Mn(II)L(H 2 O) 2 ](ClO 4 ) 2 was synthesized by cyclo-condensation of N , N ′-bis(3-formyl-5- n -butylsalicylidene)-ethylenediimine and diethylenetriamine in the presence of Cu 2+ and Mn 2+ . The crystal structure of the complex was determined. Variable-temperature magnetic susceptibilities and cyclic voltammograms of the complex were measured. [Cu(II)Mn(II)L(H 2 O) 2 ](ClO 4 ) 2 displays very strong antiferromagnetic exchange and undergoes a one-electron transfer process.
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