Author： Sun Zhen-Gang Dong Da-Peng Li Jing Cui Lian-Yi Zhu Yan-Yu Zhang Jing Zhao Yan You Wan-Sheng Zhu Zai-Ming
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.60, Iss.23, 2007-12, pp. : 2541-2547
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Abstract
In the presence of ethylenediamine template agents, a metal(II) phosphonate, [NH3CH2CH2NH3][Fe2(O3PCH(OH)CO2)2(H2O)2] · 2H2O (1) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction as well as infrared spectroscopy, elemental analysis and thermogravimetric analysis. The compound crystallines in the monoclinic space group P21/n: Crystal data for 1: a = 8.4523(8) Å, b = 9.8196(9) Å, c = 10.9217(10) Å, β = 105.9500(10)°, V = 871.58(14) Å, Z = 2, Dc = 2.103 g cm-3, R1 = 0.0290, wR2 = 0.0811. The Fe (II) cation is octahedrally coordinated by six oxygen atoms from the three ligands and one coordinated water molecule to form a 2D layered structure with a one-dimensional channel system in the a-axis direction.
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