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High-Resolution Fourier Transform Emission Spectroscopy of the B²Σ⁺ (v = 0)–X²Σ⁺ (v = 0) Transition of the PN⁺ Ion

Author： Imajo T. Tokieda K. Nakashima Y. Tanaka K. Tanaka T.

Publisher： Academic Press

ISSN： 0022-2852

Source： Journal of Molecular Spectroscopy, Vol.204, Iss.1, 2000-11, pp. : 21-25

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

Ultraviolet emission spectrum of the B²Σ⁺ (v = 0)–X²Σ⁺ (v = 0) transition of the PN⁺ ion has been observed at a resolution of 0.05 cm^-1 by a Fourier transform spectrometer. The rotational analysis led to a great improvement of rotational constants in the B²Σ⁺ (v = 0) and X²Σ⁺ (v = 0) states as well as to the first determination of centrifugal distortion constants for both levels and spin–rotation interaction constant in the X²Σ⁺ (v = 0) state. Rotational perturbation in the B²Σ⁺ (v = 0) state was observed.

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