The Chemical Physics of Solid Surfaces

Author: King   D. A.  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780444601551

P-ISBN(Paperback): 9780444814685

P-ISBN(Hardback):  9780444814685

Subject: O6-0 chemical principle and method

Language: ENG

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Description

The Chemical Physics of Solid Surfaces, Volume 6: Coadsorption, Promoters, and Poisons focuses on the processes, reactions, and approaches involved in coadsorption and the functions of promoters and poisons in synthesis and reactions.

The selection first offers information on adsorbate-adsorbate interactions on metal surfaces and interaction between alkali metal adsorbates and adsorbed molecules. Discussions focus on coadsorption of alkali metals and other molecules; model experiments of catalyst promotion; effective medium theory; direct and indirect hybridization effects; and elastic interaction between adsorbates. The publication then ponders on coadsorption of carbon monoxide and hydrogen on metal surfaces and adsorption on bimetallic surfaces.

The manuscript examines the chemical properties of alloy single crystal surfaces and promotion in ammonia synthesis. Topics include substrate dependence of nitrogen adsorption and ammonia synthesis; effects of promotion on nitrogen dissociation and ammonia synthesis; and theoretical modeling. The text then elaborates on promotion in the Fischer-Tropsch hydrocarbon synthesis, promoters and poisons in the water-gas shift reaction, and strong metal-support interactions.

The selection is a recommended reference for physicists and readers interested in coadsorption, promoters, and poisons.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 10

Table of Contents

pp.:  10 – 10

Preface

pp.:  10 – 16

Chapter 2. Theory of the coadsorption of H2O and CO with K on the Pt(111) surface

pp.:  44 – 66

Chapter 3. Interaction between alkali metal adsorbates and adsorbed molecules (CO; H2O)

pp.:  66 – 128

Chapter 4. Coadsorption of carbon monoxide and hydrogen on metal surfaces

pp.:  128 – 172

Chapter 5. Adsorption on bimetallic surfaces

pp.:  172 – 240

Chapter 7. Promotion in ammonia synthesis

pp.:  240 – 284

Chapter 8. Promotion in the Fischer-Tropsch hydrocarbon synthesis

pp.:  284 – 302

Chapter 9. Promoters and poisons in the water-gas shift reaction

pp.:  302 – 326

Chapter 10. Strong metal-support interactions

pp.:  326 – 356

Index

pp.:  356 – 363