Description
The behaviour of polymers in multi-component and multiphase systems such as solutions, blends and interfaces derived from both natural and synthetic sources and the subsequent influence of this on their physical properties is the theme of this book. Important new material on multiphase polymer systems such as block copolymers and liquid crystalline polymers is provided, and the solution and surface properties of enzymes and surface active polymers is described both theoretically and experimentally. The application of theory to the development of new cellulosic materials is particularly noteworthy.
The relationship between end-use properties, such as adhesion, wetting, and colloidal stability, and molecular structure at the interface is addressed. Examples include the capillary pressure of nylon microporous membranes, a new technique for characterizing the adhesion between incompatible polymers, and the influence of the glass transition temperature at the fiber/matrix interface on interfacial shear strength.
Characterization of polymer films, both electrochemically and via optical techniques is covered and the interactions of amphiphilic ions with polyacrylate polymer are described. The final two chapters introduce the topic of enzyme mobility at an interface and show how this may affect their role as biological catalysts.
Chapter
Chapter 2. Emulsion polymerization with oligomeric diblock macromonomer stabilizers
pp.:
36 – 56
CHAPTER 3. INVESTIGATIONS OF THE POLYMER INTERPHASE VIA THE SYNTHESIS OF WELL-DEFINED SELECTIVELY DEUTERATED BLOCK COPOLYMERS
pp.:
56 – 78
Chapter 4. Synthesis and Morphological Studies of (AB)n Multiblock Copolymers
pp.:
78 – 102
Chapter 5. Study of blends with narrow molecular weight distribution: hydrogen and deuterium labeled polystyrene and poly(vinyl methyl ether)
pp.:
102 – 122
Chapter 6. The nature of the crystal/amorphous interface in polyethylene and its blends
pp.:
122 – 146
Chapter 7. Hydrogen Bonding Interaction in Polymer Blends
pp.:
146 – 164
Chapter 8. Quick Quenching of Polymer Blends
pp.:
164 – 186
Chapter 9. Dynamic Light Scattering of Ternary Polymer Solutions
pp.:
186 – 210
Chapter 10. Local Dynamics of Polymer Chains in Restrictive Environment
pp.:
210 – 222
Chapter 11. Novel orientation techniques for the preparation of highperformance materials from semi-flexible polymers such as the cellulosics
pp.:
222 – 234
Chapter 12. Isotropic-nematic phase transitions in polymer networks deformed in the dry and swollen states
pp.:
234 – 258
Chapter 13. Polymerization and thermal quench induced phase separation in polymer dispersed nematic liquid crystals
pp.:
258 – 286
Chapter 14. Characterization of Lyotropic Polysaccharide Liquid Crystal Blends
pp.:
286 – 312
Chapter 15. Effect of high temperature annealing on the capillarity of polyamide microporous membranes
pp.:
312 – 328
Chapter 16. A technique for accurate characterization of adhesion between incompatible polymers
pp.:
328 – 352
Chapter 17. The Influence of the Fiber/Matrix Interface on Local Glass Transition Temperature
pp.:
352 – 372
Chapter 18. Species Transport and Distribution in Thin Polymer Films Using Eigenmode Analysis in Integrated Optical Structures
pp.:
372 – 398
CHAPTER 19. COMPOSITE CONDUCTIVE POLYMERS CHARACTERIZED BY THE EQCM TECHNIQUE
pp.:
398 – 420
Chapter 20. Determination of polycarboxylates in water samples by means of polyelectrolyte titration
pp.:
420 – 436
Chapter 21. Size of Tetradecyltrimethylammonlum Bromide Aggregates on Polyacrylic Acid in Solution by Dynamic Fluorescence
pp.:
436 – 458
Chapter 22. Catalysis of Hydrolysis by Proteases at the Protein-Solution Interface
pp.:
458 – 478
CHAPTER 23. LATERAL DIFFUSION OF LIPASE AT THE AIR/WATER INTERFACE
pp.:
478 – 492
Author Index
pp.:
492 – 493
Subject Index
pp.:
493 – 499