Clays and Hydrosilicate Gels in Nuclear Fields ( Volume 26 )

Publication series :Volume 26

Author: Meunier   A.  

Publisher: Elsevier Science‎

Publication year: 1992

E-ISBN: 9780444596826

P-ISBN(Paperback): 9780444895707

P-ISBN(Hardback):  9780444895707

Subject: P5 Geology;TB3 Engineering Materials;X Environmental Science, Safety Science

Language: ENG

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Description

Research on issues relating to nuclear waste storage plays an important role in contributing to finding good solutions to a problem that concerns mankind's future, predicting the durability of engineered barriers and determining the kinetics of alteration processes. The latter is now one of the vital questions in the scientific community concerned with clay minerals and hydrosilicate gels.


The 20 papers published in this volume bring together the experience of specialists on topics such as hydrosilicate gels and early mineral phase crystallization, clay mineral reactions and crystallochemistry of clay minerals. The contributions are of world-wide interest, and will help to stimulate future research and analysis in this field.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 8

Preface

pp.:  8 – 10

Chapter 2. Archaeological glasses as modelling of the behavior of buried nuclear waste glass

pp.:  24 – 40

Chapter 3. Rate and mechanism of the reaction of silicates with cement pore fluids

pp.:  40 – 54

Chapter 4. Early phyllosilicates formed by alteration of R7T7 glass in water at 250°C

pp.:  54 – 66

Chapter 5. Retention of radionuclides in poorly organized phases in the near field of a HLW nuclear disposal facility

pp.:  66 – 78

Chapter 6. Neptunium (V and VI) exchange between silicate gels and aqueous solutions

pp.:  78 – 86

Chapter 7. Naturel gels in the Yucca Mountain area, Nevada, USA

pp.:  86 – 94

Chapter 8. Experimental alteration of R7T7 glass in salt brines at 90°C and 150°C

pp.:  94 – 104

Chapter 9. Dioctahedral smectite reactions at elevated temperatures: Effects of K-availability, Na/K ratio and ionic strength

pp.:  104 – 120

Chapter 10. Mineralogy and kinetics of alteration of a mixed-layer kaolinite/smectite in nuclear waste disposal simulation

pp.:  120 – 132

Chapter 11. Conversion time from smectite to illite. A preliminary study

pp.:  132 – 138

Chapter 12. Smectite-to-illite conversion in natural hydrothermal systems

pp.:  138 – 154

Chapter 13. The actual distribution of octahedral cations in 2:1 clay minerals: Results from clay synthesis

pp.:  154 – 176

Chapter 14. Clay mineral transformations in static hydrothermal conditions within a simulated engineered barrier for nuclea

pp.:  176 – 186

Chapter 15. Radiometric emanation method (REM) for the characterization of morphological changes in K-bentonite during its interaction with some organic compounds

pp.:  186 – 192

Chapter 16. Saponitic clays from the Madrid basin: Accessory-minerals influence in hydrothermal reactivity

pp.:  192 – 208

Chapter 17. Sorption and speciation of heavy metals on hydrous Fe and Mn oxides. From microscopic to macroscopic

pp.:  208 – 232

Chapter 18. Sorption mechanisms of three actinides on a clayey mineral

pp.:  232 – 246

Chapter 19. Sorption of major cations on pure and composite clayey materials

pp.:  246 – 252

Chapter 20. Studies on the interactions of HDPY-vermiculite with radioiodine

pp.:  252 – 258

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