Dynamic Nuclear Magnetic Resonance Spectroscopy

Author: Jackman   Lloyd  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780323143585

P-ISBN(Paperback): 9780123788504

P-ISBN(Hardback):  9780123788504

Subject: O6-0 chemical principle and method

Language: ENG

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Description

Dynamic Nuclear Magnetic Resonance Spectroscopy provides an overview of the state of knowledge in dynamic nuclear magnetic resonance (DNMR) spectroscopy. The early chapters describe the theoretical basis and practical techniques which have or will be used for extracting kinetic data from DNMR spectra. The subsequent chapters provide reviews of the many areas in which DNMR spectroscopy has been applied.

Key topics covered include nuclear exchange processes; band-shape analysis; application of nonselective pulsed NMR experiments: diffusion and chemical exchange; spin-spin relaxation time determination; rotation about single and double bonds in organic molecules; and dynamic molecular processes in inorganic and organometallic compounds. Also discussed are studies on stereochemical nonrigidity in organometallic and metal carbonyl compounds; fluxional allyl complexes; carbonium ion rearrangements; and proton transfer processes. It is hoped that this volume will provide a literature guide, source book, and progress report which will be helpful to all those who will continue or will begin work in this field.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 12

List of Contributors

pp.:  12 – 14

Preface

pp.:  14 – 18

Chapter 2. Delineation of Nuclear Exchange Processes

pp.:  40 – 62

Chapter 3. Band-Shape Analysis

pp.:  62 – 100

Chapter 4. Application of Nonselective Pulsed NMR Experiments—Diffusion and Chemical Exchange

pp.:  100 – 148

Chapter 5. Determination of Spin–Spin Relaxation Times in High-Resolution NMR

pp.:  148 – 180

Chapter 6. Rotation about Single Bonds in Organic Molecules

pp.:  180 – 220

Chapter 7. Rotation about Partial Double Bonds in Organic Molecules

pp.:  220 – 270

Chapter 8. Dynamic Molecular Processes in Inorganic and Organometallic Compounds

pp.:  270 – 334

Chapter 9. Stereochemically Nonrigid Metal Chelate Complexes

pp.:  334 – 394

Chapter 10. Stereochemical Nonrigidity in Organometallic Compounds

pp.:  394 – 458

Chapter 11. Fluxional Allyl Complexes

pp.:  458 – 506

Chapter 12. Stereochemical Nonrigidity in Metal Carbonyl Compounds

pp.:  506 – 540

Chapter 13. Dynamic NMR Studies of Carbonium Ion Rearrangements

pp.:  540 – 560

Chapter 14. Conformational Processes in Rings

pp.:  560 – 638

Chapter 15. Proton Transfer Processes

pp.:  638 – 666

Subject Index

pp.:  666 – 678

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