Catalysis by Acids and Bases ( Volume 20 )

Publication series :Volume 20

Author: Imelik   B.;Naccache   C.;Coudurier   G.  

Publisher: Elsevier Science‎

Publication year: 1985

E-ISBN: 9780080960548

P-ISBN(Paperback): 9780444424495

P-ISBN(Hardback):  9780444424495

Subject: O643.3 catalytic

Language: ENG

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Description

Because of the great importance of acid catalysis in the petrochemical industry, extensive research has been carried out during the last 30 years concerning the fundamental and applied aspects of catalysis by acids. In contrast, base-catalyzed reactions have received little attention in heterogeneous catalysis. The aim of this symposium was to evaluate our knowledge of the important area of acid and base catalysis and to cover a broad range of solids, zeolite chemistry being only one aspect of heterogeneous catalysis.

Chapter

Front Cover

pp.:  1 – 4

Catalysis by Acids and Bases

pp.:  4 – 5

Copyright Page

pp.:  5 – 6

Contents

pp.:  6 – 10

Foreword

pp.:  12 – 14

Preface

pp.:  14 – 16

Chapter 2. A TPD, FT-IR and catalytic study on the interaction of methanol with pure and KOH doped TiO2 anatase

pp.:  30 – 40

Chapter 3. Acid and base strength of alumina-magnesia mixed oxides

pp.:  40 – 48

Chapter 4. Influence of the operating conditions on the morphology and acidity of K2CO3/γ Al2O3

pp.:  48 – 60

Chapter 5. Acidic reactions on some transition metal oxide systems

pp.:  60 – 72

Chapter 6. Modification of the acidity and basicity of the surface oxide catalysts

pp.:  72 – 82

Chapter 7. Basic molecular sieve catalysts/side-chain alkylation of toluene by methanol

pp.:  82 – 90

Chapter 8. Importance of the acid strength in heterogeneous catalysis

pp.:  90 – 106

Chapter 9. Structure and acidic properties of high silica faujasites

pp.:  106 – 116

Chapter 10. Acidity in zeolites

pp.:  116 – 126

Chapter 11. Acidic and basic properties of aluminas in relation to their properties as catalysts and supports

pp.:  126 – 142

Chapter 12. Reactivity of isopropanol on K- and Cs-exchanged ZSM-5 and mordenite

pp.:  142 – 150

Chapter 13. Quantitation and modification of catalytic sites in ZSM-5

pp.:  150 – 162

Chapter 14. Characterization of acidic properties of heteropoly compounds in relation to heterogeneous catalysis

pp.:  162 – 172

Chapter 15. Heteropoly compounds : solid acids with guarded protons

pp.:  172 – 182

Chapter 16. Heteropolyacids as solid-acid catalysts

pp.:  182 – 192

Chapter 17. New covalent boron (III)-molybdenum (VI) mixed oxo model compounds as eligible hetero bimetallic catalysts for propylene epoxidation

pp.:  192 – 198

Chapter 18. Catalytic activities and selectivities of crystalline ε-Zr(HPO4)2

pp.:  198 – 206

Chapter 19. Calorimetric study of adsorption of ammonia at 420 K on bismuth molybdate (2 : 1)

pp.:  206 – 212

Chapter 20. Skeletal isomerization of n-butene over modified boron phosphate

pp.:  212 – 220

Chapter 21. Catalytic application of hydrophobic properties of high- silica zeolites. II. Esterification of acetic acid with butanols

pp.:  220 – 228

Chapter 22. The mechanism of n-pentane transformation over solid superacids Al2O3/AlCl3

pp.:  228 – 236

Chapter 23. Factors affecting the deactivation of zeolites by coking

pp.:  236 – 256

Chapter 24. Valorisation des oléfines : oligomérisation catalysée par le trifluorure de bore

pp.:  256 – 268

Chapter 25. Upgrading of C4 cracking cuts with acid catalysts

pp.:  268 – 280

Chapter 26. Hydrocracking of n-heptane on Pt-HZSM-5. Effect of calcination and reduction conditions

pp.:  280 – 288

Chapter 27. Transition ions exchanged zeolites as cracking catalysts

pp.:  288 – 298

Chapter 28. Characterization of acid catalysts by use of model reactions

pp.:  298 – 314

Chapter 29. Application de la résonance magnétique nucléaire à l'étude de la distribution et de l'acidité de l'eau de constitution des solides

pp.:  314 – 326

Chapter 30. Microcalorimetric characterization of acidity and basicity of various metallic oxides

pp.:  326 – 334

Chapter 31. Determination de l'acidité de catalyseurs solides en milieu aqueux à l'aide d'un marqueur cinétique

pp.:  334 – 340

Chapter 32. Degradation mechanism of 3-methyl-pentane on a supported superacid catalyst studied by the 13C isotopic tracer technique

pp.:  340 – 350

Chapter 33. Relationship between catalytic activity and acid strength of LaHY zeolites in cumene cracking and o-xylene isomerization

pp.:  350 – 358

Chapter 34. Acid properties of a bidimensional zeolite

pp.:  358 – 366

Chapter 35. Thermal stability and acidity of Al3+ cross linked smectites

pp.:  366 – 376

Chapter 36. Mechanisms of the acid-catalyzed isomerization of paraffins

pp.:  376 – 386

Chapter 37. Acidic catalysis and radical assistance

pp.:  386 – 398

Chapter 38. Alkylation of benzene with propene on benzyl sulfonic acid siloxane catalysts

pp.:  398 – 406

Chapter 39. The conversion of dimethylether over Pt/H-ZSM5. A bifunctional catalyzed reaction

pp.:  406 – 414

Chapter 40. Acid-catalyzed conversion of n-decane over high-silica faujasites

pp.:  414 – 424

Chapter 41. A new approach to the cracking of alkanes as a test reaction for solid acid catalysts

pp.:  424 – 434

Chapter 42. Comparison of the reactions of ethylcyclohexane and 2-methylheptane on Pd/LaY zeolite

pp.:  434 – 442

Chapter 43. Primary cracking modes of long chain paraffinic hydrocarbons in open acid zeolites

pp.:  442 – 452

Chapter 44. Catalyseurs isolants et acidité - les acides paradoxaux

pp.:  452 – 462

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