Multidimensional Solid-State NMR and Polymers

Author: Schmidt-Rohr   Klaus;Spiess   Hans Wolfgang  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780080925622

P-ISBN(Paperback): 9780126266306

P-ISBN(Hardback):  9780126266306

Subject: O63 Polymer Chemistry (Polymer)

Language: ENG

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Description

NMR spectroscopy is the most valuable and versatile analytical tool in chemistry. While excellent monographs exist on high-resolution NMR in liquids and solids, this is the first book to address multidimensional solid-state NMR. Multidimensional techniques enable researchers to obtain detailed information about the structure, dynamics, orientation, and phase separation of solids, which provides the basis of a better understanding of materials properties on the molecular level.Dramatic progress-much of it pioneered by the authors-has been achieved in this area, especially in synthetic polymers. Solid-state NMR now favorably competes with well-established techniques, such as light, x-ray, or neutron scattering, electron microscopy, and dielectric and mechanical relaxation.
The application of multidimensional solid-state NMR inevitably involves use of concepts from different fields of science. This book also provides the first comprehensive treatment of both the new experimental techniques and the theoretical concepts needed in more complex data analysis. The text addresses spectroscopists and polymer scientists by treating the subject on different levels; descriptive, technical, and mathematical approaches are used when appropriate. It presents an overview of new developments with numerous experimental examples and illustrations, which will appeal to readers interested in both the information content as well as the potential of solid-state NMR. The book also contains many pr

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 14

Preface

pp.:  14 – 16

Acknowledgements

pp.:  16 – 18

NMR Acronyms and Abbreviations

pp.:  18 – 20

Chapter 1. Introduction

pp.:  20 – 32

Chapter 2. Principles of NMR of Organic Solids

pp.:  32 – 88

Chapter 3. High-Resolution NMR Techniques for Solids

pp.:  88 – 154

Chapter 4. Fourier Theory for 1D and 2D NMR

pp.:  154 – 190

Chapter 5. Short Review of Structure and Dynamics of Solid Polymers

pp.:  190 – 201

Chapter 6. Multidimensional Separation and Correlation

pp.:  201 – 255

Chapter 7. Polymer Dynamics: Multidimensional Exchange Experiments

pp.:  255 – 296

Chapter 8. Multidimensional Exchange NMR Above the Glass Transition

pp.:  296 – 316

Chapter 9. Multidimensional Spectra, Correlation Functions, and Stochastic Processes

pp.:  316 – 338

Chapter 10. Time-Domain Signals for Multidimensional Spectra

pp.:  338 – 360

Chapter 11. Multidimensional Exchange Spectra: Simulations, Models, Angle Distributions

pp.:  360 – 379

Chapter 12. Determination of Order in Polymers by Multidimensional NMR

pp.:  379 – 421

Chapter 13. Domain Sizes and Internuclear Distances From Spin Diffusion and Dipolar Couplings

pp.:  421 – 459

APPENDICES

pp.:  459 – 485

Index

pp.:  485 – 502

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