Description
Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems.
The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems.
Chapter
Chapter 3. Gas Phase Polymerization of Propene with MgCl2 Supported Catalyst
pp.：
48 – 58
Chapter 4. Ethylene Polymerization in Gas–Phase and Slurry Reactors
pp.：
58 – 74
Chapter 5. Differences in Kinetic Parameters of Various Kinds of MgCl2–Sup–ported High Yield Catalysts
pp.：
74 – 82
Chapter 6. Kinetic Profile of Polymerization with Cr–Oxide/SiO2 Catalyst
pp.：
82 – 106
Chapter 7. Effects of the Structure of External Alkoxy Silane Donor in High Activity Ziegler–Natta Catalyst on the Microstructure of Polypropylene
pp.：
106 – 126
Chapter 8. Active Center Selection and Propene Polymerization Control with the New Supported Ziegler–Natta Catalysts
pp.：
126 – 136
Chapter 9. Control of the Catalyst and Polymer Properties of Linear Polyethylenes
pp.：
136 – 150
Chapter 10. Easy Conversion of Aspecific into Isospecific Sites
pp.：
150 – 158
Chapter 11. A 13C CP–MAS NMR and Elemental Analysis Study of Adsorption of Silyl Ethers on the MgCl2–Supported Ziegler–Natta Catalysts
pp.：
158 – 166
Chapter 12. Infrared Characterization of Supported Propylene Polymerization Catalysts–A Link to Catalyst Performance
pp.：
166 – 174
Chapter 13. Microtacticity Distribution of Polypropylenes Prepared with MgCl2 Supported Ti Catalyst Systems
pp.：
174 – 184
Chapter 14. Development of SiO2–Supported Type Catalyst for Propylene Molymerization
pp.：
184 – 196
Chapter 15. Effect of Silane Compounds on Catalyst Isospecificity – A Plausible Model Based on MO Calculation
pp.：
196 – 204
Chapter 16. 13C NMR Investigation on Lewis Base Activation Effect in High Yield Supported Ziegler–Natta Catalysts
pp.：
204 – 220
Chapter 17. A New Electron Donor for the Stereospecific Polymerization of Propene
pp.：
220 – 230
Chapter 18. Formation of Cationic Species and Additive Effect of Ethyl Benzoate on Polymerization of Isobutene and Styrene with TiCl3 –Alkylaluminum Catalyst
pp.：
230 – 242
Chapter 19. Co– and Terpolymerization of Ethene and Higher α–Olefins with MgH2 Supported Ziegler Catalysts : New Mechanistic Insight via the True Reactivity Ratios
pp.：
242 – 264
Chapter 20. Co– and Terpolymerization of Ethylene, Propylene and Butadiene with Supported Titanium Catalyst
pp.：
264 – 282
Chapter 21. Kinetics of Ethylene –Propylene Copolymerization over MgCl2 –Supported Catalysts
pp.：
282 – 296
Chapter 22. A Study on the Active Sites of a Primary Type of MgCl2–Supported Catalyst by Ethylene–Propylene Copolymerization
pp.：
296 – 304
Chapter 23. Syntheses of Terminally Hydroxylated Polyolefins Using Zn (C2H5)2 and Oxygen as Chain Transfer and Quenching Reagents
pp.：
304 – 320
Chapter 24. Conversion of Titanacyclobutane Complexes for Ring Opening Metathesis Polymerization into Ziegler–Natta Catalysts
pp.：
320 – 332
Chapter 25. Modification of High cis– 1, 4 Polybutadiene by Neodymium Catalyst
pp.：
332 – 342
Chapter 26. Homo– and Co–polymerization of Ethylene with the Highly Active TiCl4/THF/MgCl2 Catalyst
pp.：
342 – 364
Chapter 27. Morphology of Nascent Polypropylene Produced by MgCl2 Supported Ti Catalyst
pp.：
364 – 374
Chapter 28. Hafnium Based Catalysts for the Polymerization of Olefins
pp.：
374 – 396
Chapter 29. High Active Ziegler–Natta Catalysts for Homo– and Copolymerization of Ethylene by Supporting a Grignard Compound and TiCl4 on SiO2
pp.：
396 – 424
Chapter 30. New Solvay SB 12 TiCl3 Polypropylene Catalyst
pp.：
424 – 444
Chapter 31. Polymerization of Cyclic Olefins with Homogeneous Catalysts
pp.：
444 – 458
Chapter 32. Syndiotactic Propylene Polymerizations with iPr[CpFlu]ZrCl2
pp.：
458 – 502
Chapter 33. Stereospecific Polymerization of α-Olefin with an Ethylene Bis (1 –Indenyl) Hafnium Dichloride and Methyl– Aluminoxane Catalyst System
pp.：
502 – 512
Chapter 34. Isotactic Polypropylene with a Soluble Metallocene Based Catalyst System – Characterization of Blown Film –
pp.：
512 – 520
Chapter 35. Propylene Polymerization by Stereorigid Metallocene Catalysts : Some New Aspects of the Metallocene Structure/Polypropylene Microstructure Correlation
pp.：
520 – 536
Chapter 36. Polymerization of Styrene and Copolymerization of Styrene with Olefin in the Presence of Soluble Ziegler–Natta Catalysts
pp.：
536 – 550
Chapter 37. Propylene Polymerizations with Silylene–Bridged Metallocene Catalysts
pp.：
550 – 554
Chapter 38. Homogeneous Ziegler–Natta Catalysts and Synthesis of Anisotactic and Thermoplastic Elastomeric Poly(propy1enes)
pp.：
554 – 594
Studies in Surface Science and Catalysis
pp.：
594 – 598
Catalytic Olefin Polymerization
( Volume 56 )
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