Interfacial and Confined Water

Author: Brovchenko   Ivan;Oleinikova   Alla  

Publisher: Elsevier Science‎

Publication year: 2008

E-ISBN: 9780080558172

P-ISBN(Paperback): 9780444527189

P-ISBN(Hardback):  9780444527189

Subject: O4 Physics;O6-0 chemical principle and method

Language: ENG

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Description

Water in the proximity of a surface (interfacial water) is abundant on the earth. It is involved in various physical and chemical processes and crucial for biological function. Despite numerous studies of interfacial water, systematic analysis of its properties is missing in scientific literature. This book is a first comprehensive review of experimental and simulation studies of water in various confining environments, such as hydrophilic and hydrophobic surfaces, surfaces of biomolecules, porous media, etc. Systematic analysis of interfacial and confined water is based on the firm physical ground, which accounts for variety of the thermodynamic states of water near the surface, surface phase transitions, surface critical behaviour, effect of confinement on the bulk and surface phase transitions of water, clustering and formation of a spanning hydrogen-bonded water network via percolation transition. This allows distinguishing between universal features, common for all fluids, and some specific water properties, related to intermolecular hydrogen bonds. Special attention is paid to the properties of hydration water, which covers biomolecules and enables their biological activity. This book provides readers with basic information on interfacial and confined water, which will be useful for scientists and engineers working in the fields of bioscienses, nanociences and nanotechnologies.

* Comprehensive review and analysis of interfacial and confined water
* Updates an

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 8

Preface

pp.:  8 – 12

Chapter 2. Surface Transitions of Water

pp.:  28 – 78

Chapter 3. Surface Critical Behavior of Water

pp.:  78 – 102

Chapter 4. Phase Diagram of Confined Water

pp.:  102 – 132

Chapter 5. Water Layers at Hydrophilic Surfaces

pp.:  132 – 162

Chapter 6. Role of Interfacial Water in Biological Function

pp.:  162 – 176

Chapter 7. Water in Low-hydrated Biosystems

pp.:  176 – 226

Chapter 8. States of Interfacial Water in Fully Hydrated Biosystems

pp.:  226 – 244

Chapter 9. Summary and Outlook

pp.:  244 – 248

References

pp.:  248 – 314

Index

pp.:  314 – 318

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