Introduction to Non-equilibrium Physical Chemistry

Author: Rastogi   R. P.  

Publisher: Elsevier Science‎

Publication year: 2007

E-ISBN: 9780080551807

P-ISBN(Paperback): 9780444521880

P-ISBN(Hardback):  9780444521880

Subject: O6 Chemistry;O6-0 chemical principle and method

Language: ENG

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Description

Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems.

Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix.

Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies.

Part IV deals w

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 8

Table of Contents

pp.:  8 – 14

PREFACE

pp.:  14 – 16

ACKNOWLEDGEMENTS

pp.:  16 – 18

COLOUR PLATE SECTION

pp.:  18 – 22

CHAPTER 1 INTRODUCTION

pp.:  22 – 30

PART ONE NON-EQUILIBRIUM STEADY STATES CLOSE TO EQUILIBRIUM

pp.:  30 – 120

PART TWO NON-LINEAR STEADY STATES – DISSIPATIVE STRUCTURE (TIME ORDER AND SPACE ORDER)

pp.:  120 – 208

PART THREE COMPLEX NON-EQUILIBRIUM PHENOMENA FAR FROM EQUILIBRIUM

pp.:  208 – 292

PART FOUR NON-EQUILIBRIUM PHENOMENA IN NATURE AND SOCIETY

pp.:  292 – 336

EPILOGUE

pp.:  336 – 342

APPENDIX I DOMAIN OF VALIDITY OF GIBBS EQUATION

pp.:  342 – 346

APPENDIX II EXTENDED IRREVERSIBLE THERMODYNAMICS

pp.:  346 – 350

APPENDIX III NON-EQUILIBRIUM MOLECULAR DYNAMICS

pp.:  350 – 354

INDEX

pp.:  354 – 358

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