Advances in Gas Phase Ion Chemistry ( Volume 3 )

Publication series :Volume 3

Author: Adams   N. G.;Babcock   L. M.  

Publisher: Elsevier Science‎

Publication year: 1998

E-ISBN: 9780080550862

P-ISBN(Paperback): 9780762302048

P-ISBN(Hardback):  9780762302048

Subject: O64 (physical chemistry) and theoretical chemistry, chemical physics

Language: ENG

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Description

Gas-phase ion chemistry is a broad field which has many applications and which encompasses various branches of chemistry and physics. An application that draws together many of these branches is the synthesis of molecules in interstellar clouds. This was part of the motivation for studies on the neutralization of ions by electrons and on isomerization in ion-neutral associations. The results of investigations of particular aspects of ion dynamics are presented in this volume. Solvation in ion-molecule reactions is discussed and extended to include multiply charged ions by the application of electrospray techniques. This volume also provides a wealth of information on reaction thermodynamics which is critical in determining reaction spontaneity and availability of reaction channels. More focused studies are also presented towards the end of this volume, relating to the ionization process and its nature.

Chapter

COVER

pp.:  1 – 6

CONTENTS

pp.:  6 – 8

LIST OF CONTRIBUTORS

pp.:  8 – 10

PREFACE

pp.:  10 – 12

CHAPTER 2. COMPLEX FORMATION IN ELECTRON–ION RECOMBINATION OF MOLECULAR IONS

pp.:  60 – 92

CHAPTER 3. REACTIVE PROBING OF THE POTENTIAL ENERGY SURFACES OF ISOMERIC IONS

pp.:  92 – 136

CHAPTER 4. DYNAMICS OF GAS-PHASE Sn2 NUCLEOPHILIC SUBSTITUTION REACTIONS

pp.:  136 – 168

CHAPTER 5. BARRIERS TO INTERNAL ROTATION IN SUBSTITUTED TOLUENES AND THEIR CATIONS: EFFECTS OF ELECTRONIC EXCITATION AND IONIZATION

pp.:  168 – 196

CHAPTER 6. THE INFLUENCE OF SOLVATION ON ION–MOLECULE REACTIONS

pp.:  196 – 266

CHAPTER 7. THERMOCHEMISTRY OF SINGLY AND MULTIPLY CHARGED IONS PRODUCED BY ELECTROSPRAY

pp.:  266 – 330

CHAPTER 8. POSITIVE ION–ELECTRON IMPACT IONIZATION CROSS SECTIONS: THEORY AND EXPERIMENT

pp.:  330 – 370

INDEX

pp.:  370 – 378

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