Structure, Fluctuation, and Relaxation in Solutions ( Volume 83 )

Publication series :Volume 83

Author: Nomura   H.;Kawaizumi   F.;Yarwood   J.  

Publisher: Elsevier Science‎

Publication year: 1995

E-ISBN: 9780080544779

P-ISBN(Paperback): 9780444823847

P-ISBN(Hardback):  9780444823847

Subject: O4 Physics;O6-0 chemical principle and method;O657 instrumental analysis (physical and chemical analysis)

Language: ENG

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Description

The results of a special research project carried out for "Molecular Approaches to Non-equilibrium Process in Solution" were presented during The 42nd Yamada Conference on "Structure, Fluctuation and Relaxation in Solution" which was held from 11-15 December, 1994. The following topics were discussed at the conference:

1. Solvation Dynamics

2. Relaxation, Fluctuation and Reaction Dynamics

3. Dynamic Structure and Reaction Mechanisms in Solutions. These topics were the main concern of this conference.

Chapter

Cover

pp.:  1 – 18

Preface

pp.:  8 – 10

Welcome Address

pp.:  14 – 16

Executive Members of Foundation

pp.:  17 – 24

Contents

pp.:  18 – 8

Chapter 1. Perspective of solution chemistry of Japan. The historical background and recent trends

pp.:  24 – 30

Chapter 2. Molecular theory of solvation processes in dipolar and non-dipolar solvents

pp.:  30 – 38

Chapter 3. An interaction-site representation of the dynamic structure factor of liquid and the solvation dynamics

pp.:  38 – 46

Chapter 4. The interplay of dielectric and mechanical relaxation in solvation dynamics

pp.:  46 – 54

Chapter 5. Fluctuating charge force fields for aqueous solutions

pp.:  54 – 64

Chapter 6. Solvation dynamics of dye molecules in polar solvents studied by time resolved hole burning Spectroscopy

pp.:  64 – 72

Chapter 7. Ultrafast measurements of the dynamics of solvation in polar and non-dipolar solvents

pp.:  72 – 82

Chapter 8. Solvent and nuclear dynamic effects on intermolecular electron transfer

pp.:  82 – 88

Chapter 9. Theory on rates of solution reactions influenced by slow fluctuations in viscous solvents, and its experimental confirmation

pp.:  88 – 98

Chapter 10. Dynamics of Brownian motion under a potential and theory on the rate of chemical reactions

pp.:  98 – 108

Chapter 11. Structural characteristics of hydrogen-bonded networks in water and ice systems

pp.:  108 – 114

Chapter 12. Structure and dynamics of supercooled and glassy aqueous ionic solutions

pp.:  114 – 122

Chapter 13. The structure and dynamics of aqueous solutions containing complex molecules

pp.:  122 – 130

Chapter 14. Liquid-liquid phase separations and critical behavior of electrolyte solutions driven by long-range and short-range interactions

pp.:  130 – 138

Chapter 15. Slow relaxation in pure and binary frozen-in systems

pp.:  138 – 146

Chapter 16. Slow dynamics in supercooled fluids

pp.:  146 – 154

Chapter 17. Density functional theory of solution dynamics

pp.:  154 – 162

Chapter 18. Dissociation and solvation in water and aqueous solutions

pp.:  162 – 172

Chapter 19. Effect of solvent, temperature, and pressure on hydrogen bonding and reorientation of water molecules

pp.:  172 – 180

Chapter 20. Collective vibrational dynamics of simple liquids

pp.:  180 – 192

Chapter 21. Mechanisms of dephasing in femtosecond time-resolved coherent Raman scattering from molecules in liquids

pp.:  192 – 200

Chapter 22. Ion solvation and ion association studied by infrared and microwave methods

pp.:  200 – 210

Chapter 23. Dynamical aspects of water by low-frequency Raman scattering

pp.:  210 – 218

Chapter 24. Ultrasonic relaxation study of fast exchange processes in mixed micelle systems of alcohol-decyltrimethylammonium bromide-water

pp.:  218 – 228

Chapter 25. Organometallic free radicals in solution

pp.:  228 – 236

Chapter 26. The structure of metal complexes of small models of glycoproteins in aqueous solution

pp.:  236 – 244

Chapter 27. Kinetic evidence for short-lived intermediates in metalloporphyrin formation

pp.:  244 – 252

Chapter 28. Structure and dynamics of solvated ions: new tendencies of research

pp.:  252 – 260

Chapter 29. The role of solvent in inorganic reaction mechanisms, as elucidated by high pressure studies

pp.:  260 – 268

Chapter 30. EXAFS of bromide ion in solvents and at air/solution interface

pp.:  268 – 276

Chapter 31. Redox properties of oxo-bridged di- and tri-nuclear complexes of heavy transition elements: stability of mixed-valence state

pp.:  276 – 284

Chapter 32. Study of the reduction of Co(NH3)4(pzCO2) 2+ by Fe(CN)6 4- in binary aqueous mixtures: an interpretation of solvent effects based on spectroscopic data

pp.:  284 – 288

Chapter 33. Ion pair of tetraalkylammonium picrates

pp.:  288 – 292

Chapter 34. Ion-pairing effects on the 59Co electric field gradients in the NMR relaxations of tripositive cobalt(Ill) complex ions

pp.:  292 – 296

Chapter 35. Concentration dependence of 59Co relaxation rates of tris(acetylacetonatao)-cobalt(Ill)in some organic solvents

pp.:  296 – 300

Chapter 36. Mechanistic study of oxidation reactions of hydroquinone, catechol, and L-ascorbic acid by dicyanobis(1,10-phenanthroline) iron(Ill) in dimethyl sulfoxide

pp.:  300 – 304

Chapter 37. Molecular orientation in fluids near solid-liquid interface as studied by the density functional method

pp.:  304 – 308

Chapter 38. The stability and dynamics of clathrate hydrates

pp.:  308 – 312

Chapter 39. Deviation of the TST rate constant through the nonlinear couplings

pp.:  312 – 316

Chapter 40. Spatial correlations in reaction-diffusion systems in nonequilibrium conditions

pp.:  316 – 320

Chapter 41. Nonlinear effects of solvation dynamics

pp.:  320 – 324

Chapter 42. Solvation dynamics studied by ultrafast transient hole burning

pp.:  324 – 328

Chapter 43. Hydrogen-bonded structure in aqueous sulfuric acid solutions

pp.:  328 – 332

Chapter 44. Raman spectroscopic study of rotational and vibrational relaxation of CF3H in the supercritical site

pp.:  332 – 336

Chapter 45. Anomalous conformational behavior of short poly(oxyethylene) chains in water: an FT-IR spectroscopic study

pp.:  336 – 340

Chapter 46. Time-resolved resonance Raman study of the recombination dynamics photodissociated carbon monoxide to sperm whale myoglobin and its mutants

pp.:  340 – 344

Chapter 47. Solvent viscosity dependence of bimolecular reaction rate constant of the excited 9-cyanoanthracene quenched by 1,3-cyctohexadiene

pp.:  344 – 348

Chapter 48. Extremely slow reorientation dynamics of molecular tracers in glassy polymers

pp.:  348 – 352

Chapter 49. Dynamics near a liquid surface: mechanisms of evaporation and condensation

pp.:  352 – 356

Chapter 50. The effect of ionic atmosphere on the tracer diffusion of micelles

pp.:  356 – 360

Chapter 51. Effect of addition of surfactant on the micelle-monomer exchange process

pp.:  360 – 364

Chapter 52. Dissipative structure in aqueous polymer solutions

pp.:  364 – 368

Chapter 53. Non-linear effects in the free energy profile of electron transfer reaction: an integral equation approach

pp.:  368 – 372

Chapter 54. Induction time of precipitation of calcium carbonate

pp.:  372 – 376

Chapter 55. Photophysical properties of viologen-linked N-alkylporphyrins and their zinc(ll) complexes in solutions

pp.:  376 – 380

Chapter 56. Conductometric study of hydrophobic properties of tris(1,10-phenanthroline) and tris(2,2'-bipyridine) complexes

pp.:  380 – 384

Chapter 57. Structure of the monohalogenocadmium(ll)complexes in N,N-dimethylformamide

pp.:  384 – 388

Chapter 58. Effect of pressure on the viscosity of aqueous cesium chloride solution at 25 oC

pp.:  388 – 392

Chapter 59. Melting behaviour in hexagonal CeCI3 and monoclinic ErCI3 crystals

pp.:  392 – 396

Chapter 60. Polarization effect on the static and dynamic properties of molten lithium iodide

pp.:  396 – 400

Chapter 61. Evaluation of thermodynamic quantities of fluid mixtures by the PY equation

pp.:  400 – 404

Chapter 62. Solvation free energy of protein reproduced by the combination of the extended scaled particle theory and the Poisson-Boltzmann equation

pp.:  404 – 408

Chapter 63. Transport properties of a spherical molecule in solvent with position-dependent viscosity

pp.:  408 – 412

Chapter 64. Liquid dynamics studied by higher order non-linear optical spectroscopy

pp.:  412 – 416

Chapter 65. Temperature dependence of singlet excitation energy migration in liquid benzene as revealed by picosecond laser photolysis

pp.:  416 – 420

Chapter 66. Solvent effect on ultra-fast electron transfer in mixed-valence biferrocene monocation

pp.:  420 – 424

Chapter 67. Translational diffusion of transient radicals studied by the transient grating method

pp.:  424 – 428

Chapter 68. Intra and intermolecular energy transfer in thermal dissociation in the gas and liquid N2O4

pp.:  428 – 432

Chapter 69. Photoelectron emission spectroscopy applied to bromide ion in solvents

pp.:  432 – 436

Chapter 70. Direct comparison between femtosecond optical Kerr effect and high-resolution light scattering measurements

pp.:  436 – 440

Chapter 71. Vibrational cooling process in solution probed by picosecond time-resolved Raman spectroscopy. Analysis of the cooling kinetics

pp.:  440 – 444

Chapter 72. Rotational relaxation of rod like molecules: diphenylacetylene in various solvents

pp.:  444 – 448

Chapter 73. Ground state recovery of phenol blue in fluids near the gas–liquid critical density

pp.:  448 – 452

Chapter 74. Dynamics of two-component liquids near the glass transition

pp.:  452 – 456

Chapter 75. Relaxation characteristics of intracellular (Na + as measured by double quantum filtered (DQf) NMR

pp.:  456 – 460

Author Index

pp.:  460 – 464

Subject Index

pp.:  464 – 470

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