Thermal Decomposition of Ionic Solids
：Chemical Properties and Reactivities of Ionic Crystalline Phases
( Volume 86 )
Publication subTitle ：Chemical Properties and Reactivities of Ionic Crystalline Phases
Publication series ：Volume 86
Author： Galwey A. K.;Brown M. E.
Publisher： Elsevier Science
Publication year： 1999
E-ISBN: 9780080542799
P-ISBN(Paperback): 9780444824370
P-ISBN(Hardback): 9780444824370
Subject： O642 chemical thermodynamics, thermochemistry, thermodynamics balance
Language： ENG
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Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.
Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructi
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