Scientific Bases for the Preparation of Heterogeneous Catalysts ( Volume 143 )

Publication series :Volume 143

Author: Gaigneaux   E.;Vos   D. E. De;Jacobs   P. A.  

Publisher: Elsevier Science‎

Publication year: 2002

E-ISBN: 9780080540740

P-ISBN(Paperback): 9780444511782

P-ISBN(Hardback):  9780444511782

Subject: O6 Chemistry;P57 mineralogy

Language: ENG

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Description

It has become a tradition that every four years, the Université Catholique de Louvain and the Katholieke Universiteit Leuven jointly organize a symposium devoted to the scientific bases for the preparation of heterogeneous catalysts. These meetings bring together researchers from academia and industry and offer a forum for discussions on the chemistry involved in the preparation of industrial heterogeneous catalysts.



This volume containing the Proceedings of the 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts consists of papers summarizing most of the 139 oral communications and posters selected by the international scientific committee, composed of 27 experts in the field of catalyst preparation, holding an industrial or academia appointment.



The contributions focus on the aspects of catalyst preparation. The main topics are: new approaches in catalyst preparation; advanced preparations of nanoporous and mesoporous catalysts; catalysts preparation for special performances and purposes; catalysts for environmental purposes; and molecular catalysis. Emphasis is put on the role that catalysis can play as an essential element of sustainable development.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 10

Foreword

pp.:  6 – 22

Contents

pp.:  10 – 6

Chapter 5. Toward a molecular understanding of noble metal catalyst impregnation

pp.:  66 – 76

Chapter 6. Support modification of cobalt based slurry phase Fischer-Tropsch catalysts

pp.:  76 – 88

Chapter 7. The effects of nature and pretreatment of surface alumina support on the catalytic nickelsilicate membrane formation

pp.:  88 – 98

Chapter 8. Supports and catalysts preparation by using metal alkoxides grafting technique

pp.:  98 – 110

Chapter 9. Combinatorial approaches for speeding up heterogeneous catalyst discovery, optimisation and scaling-up

pp.:  110 – 114

Chapter 10. High surface area metal oxides from matrix assisted preparation in activated carbons

pp.:  114 – 122

Chapter 11. Effects of the impregnating and drying process factors on mechanical properties of a PCoMo/Al2O3 hydrotreating catalyst

pp.:  122 – 132

Chapter 13. Influence of CeO2 content on Rh/TiO2 monolithic catalysts for N2O decomposition

pp.:  132 – 142

Chapter 14. Pt combustion catalysts prepared from W/O microemulsions

pp.:  142 – 152

Chapter 15. Preparation of stable catalysts for N2O decomposition under industrial conditions

pp.:  152 – 162

Chapter 16. The Anderson-type heteropolyanions in the synthesis of alumina- and zeolite- supported HDS oxidic precursors

pp.:  162 – 170

Chapter 17. Sol-gel preparation of pure and silica-dispersed vanadium and niobium catalysts active in oxidative dehydrogenation of propane

pp.:  170 – 180

Chapter 18. Preparation of nickel-modified ceramic filters by the urea precipitation method for tar removal from biomass gasification gas

pp.:  180 – 188

Chapter 19. Preparation of gold-titanosilicate catalysts for vapor-phase propylene epoxidation using H2 and O2

pp.:  188 – 198

Chapter 20. Sol-gel synthesis of colloids and triflates containing hybrid type catalysts

pp.:  198 – 206

Chapter 21. Preparation of zeogrids through interposed stapling and fusion of MFI zeolite type nanoslabs

pp.:  206 – 214

Chapter 22. Large scale synthesis of carbon nanofibers by catalytic decomposition of hydrocarbon

pp.:  214 – 222

Chapter 23. Synthesis and characterization of carbon nanofiber supported ruthenium catalysts

pp.:  222 – 230

Chapter 24. Synthesis of high pore volume and specific surface area mesoporous alumina

pp.:  230 – 238

Chapter 25. Investigation on acidity of zeolites bound with silica and alumina

pp.:  238 – 248

Chapter 26. Preparation of BN catalyst supports from molecular precursors. Influence of the precursor on the properties of the B N ceramic

pp.:  248 – 260

Chapter 27. Monitoring of the particle size of MoSx nanoparticles by a new microemulsion- based synthesis

pp.:  260 – 268

Chapter 28. Transition metal phosphides. Novel hydrodenitrogenation catalysts

pp.:  268 – 278

Chapter 29. The application of non-hydrothermally prepared stevensites as support for hydrodesulfurization catalysts

pp.:  278 – 288

Chapter 30. NiMo/HNaY(x)-Al2O3 catalysts for the hydrodesulfurization of hindered dibenzothiophenes: effect of the preparation method

pp.:  288 – 298

Chapter 31. Chiral dirhodium catalysts confined in porous hosts

pp.:  298 – 308

Chapter 32. Synthesis and characterization of zeolite encaged enzyme-mimetic copper histidine complexes

pp.:  308 – 316

Chapter 33. Strategies for the heterogenization of rhodium complexes on activated carbon

pp.:  316 – 326

Chapter 34. Heterogeneous metathesis initiators

pp.:  326 – 334

Chapter 35. Preparation of physically heterogeneous and chemically homogeneous catalysts on the base of metal complexes immobilized in polymer gels

pp.:  334 – 342

Chapter 36. Hydrocracking catalyst to produce high quality diesel fraction

pp.:  342 – 352

Chapter 37. Thermostable yttria-doped inorganic oxide catalyst supports for high temperature reactions

pp.:  352 – 358

Chapter 38. Preparation and characterization of WOx-CeO2 catalysts

pp.:  358 – 366

Chapter 39. Preparation of iridium catalysts by deposition precipitation: room temperature oxidation of CO

pp.:  366 – 374

Chapter 40. New approach to preparation and investigation of active sites in sulfated zirconia catalysts for skeletal isomerization of alcanes

pp.:  374 – 382

Chapter 41. Supported ruthenium carbido-cluster catalysts for the catalytic removal of nitrogen monoxide and sulfur dioxide: the preparation process monitored by sulfur K-edge X-ray absorption near-edge structure

pp.:  382 – 390

Chapter 42. Catalytic transformation of dichloromethane over Y and X zeolites

pp.:  390 – 398

Chapter 43. Preparation of new solid super-acid catalyst, titanium sulfate supported on zirconia and its acid catalytic properties

pp.:  398 – 408

Chapter 44. Superacid WOx/ZrO2 catalysts for isomerization of n-hexane and for nitration of benzene

pp.:  408 – 418

Chapter 45. Preparation of copper-oxide catalyst systems for hydrogenation

pp.:  418 – 428

Chapter 46. Application of experimental design for NOx reduction by Pd–Cu catalysts

pp.:  428 – 436

Chapter 47. Marked difference of catalytic behavior by preparation methods in CH4 reforming with CO2 over Mo2C and WC catalysts

pp.:  436 – 446

Chapter 48. Synthesis and properties of new catalytic systems based on zirconium dioxide and pentasils for process of NOx selective catalytic reduction by hydrocarbons

pp.:  446 – 456

Chapter 49. Preparation of chitosan based catalysts for several reactions of liquid phase hydrogenation

pp.:  456 – 464

Chapter 50. Preparation of Mo/Al2O3 sulfide catalysts modified by Ir nanoparticles

pp.:  464 – 474

Chapter 51. Peptization mechanisms of boehmite used as precursors for catalysts

pp.:  474 – 484

Chapter 52. Influence of the treatment of Y zeolite by ammonium hexafluorosilicate on physicochemical and catalytic properties: application for chlororganics destruc- tion

pp.:  484 – 492

Chapter 53. Preparation of SiO2 modified SnO2 and ZrO2 with novel thermal stability

pp.:  492 – 502

Chapter 54. Control of the textural properties of cesium 12-molybdophosphate-based supports

pp.:  502 – 510

Chapter 55. MnOx/CeO2–ZrO2 and MnOx/WO3–TiO2 catalysts for the total oxidation of methane and chlorinated hydrocarbons

pp.:  510 – 520

Chapter 56. Catalytic behaviour of Rh-supported catalysts on lamellar and zeolitic structures by anchoring of organometallic compound

pp.:  520 – 530

Chapter 57. The use of sol-gel technique to prepare the TiO2–A1203 binary system over a wide range of Ti–Al ratios

pp.:  530 – 538

Chapter 58. Catalytic performance in the complete acetone oxidation of manganese and cobalt oxides supported on alumina and silica

pp.:  538 – 548

Chapter 59. Unsupported and supported manganese oxides used in the catalytic combustion of methyl-ethyl-ketone

pp.:  548 – 558

Chapter 60. Ni/Hβ zeolite catalysts prepared by the deposition-precipitation method

pp.:  558 – 568

Chapter 61. Sol-gel Al2O3 structure modification by Ti and Zr addition. A NMR study

pp.:  568 – 576

Chapter 62. Promotion of Ru/ZrO2 catalysts by platinum

pp.:  576 – 586

Chapter 63. Catalysts based on RhMo6 heteropolymetalates. Bulk and supported preparation and characterisation

pp.:  586 – 596

Chapter 64. Metallosilicate mesoporous catalysts prepared by incorporation of transition metals in the MCM-41 molecular sieves and their catalytic activity in selective oxidation of aromatics (styrene and benzene)

pp.:  596 – 606

Chapter 65. Controlled surface modification of alumina-supported Mo or Co–Mo sulfides by surface organometallic chemistry

pp.:  606 – 614

Chapter 66. Novel one step synthesis of cobalt (II) phtalocyanine-hydrotalcite catalysts for mercaptan oxidation in light oil sweetening

pp.:  614 – 622

Chapter 67. Structural and catalytic properties of Zr-Ce-Pr-O xerogels

pp.:  622 – 630

Chapter 68. Influence of the precursor (nature and amount) on the morphology of MoO3 crystallites supported on silica

pp.:  630 – 640

Chapter 69. Single step synthesis of metal catalysts supported on porous carbon with controlled texture

pp.:  640 – 648

Chapter 70. Ag/SiO2 and Cu/SiO2 cogelled xerogel catalysts for benzene combustion and 2-butanol dehydrogenation

pp.:  648 – 658

Chapter 71. Preparation of zeolite catalysts for dehydrogenation and isomerization of n-butane

pp.:  658 – 668

Chapter 72. The application of well-dispersed nickel nanoparticles inside the mesopores of MCM-41 by use of a nickel citrate chelate as precursor

pp.:  668 – 680

Chapter 73. Preparation of Ce–Zr–O composites by a polymerized complex method

pp.:  680 – 690

Chapter 74. Sol–gel routes for the preparation of heterogeneous catalyst based on Ru, Rh, Pd supported metals

pp.:  690 – 700

Chapter 75. Development of novel heterogeneous catalysts for oxidative reactions: prepa- ration and performance of Co–Nx catalysts in partial oxidation of toluene and n-butane

pp.:  700 – 708

Chapter 76. Synthesis and modification of basic mesoporous materials for the selective etherification of glycerol

pp.:  708 – 718

Chapter 77. Carbon nanotubes: a highly selective support for the C=C bond hydrogenation reaction

pp.:  718 – 726

Chapter 78. Raman studies of the templated synthesis of zeolites

pp.:  726 – 736

Chapter 79. Templateless synthesis of catalysts with narrow mesoporous distribution

pp.:  736 – 744

Chapter 80. Control of pore structures of titanias and titania/aluminas using complexing agents

pp.:  744 – 752

Chapter 81. Tungstophosphoric acid immobilized in polyvinyl alcohol hydrogel beads as heterogeneous catalyst

pp.:  752 – 760

Chapter 82. Functionalized SiMCM-41 as support for heteropolyacid based catalysts

pp.:  760 – 768

Chapter 83. Influence of the preparation method on the surface properties and activity of alumina-supported gallium oxide catalysts

pp.:  768 – 778

Chapter 84. Preparation and properties of bimetallic Ru–Sn sol–gel catalysts: the influence of catalyst reduction

pp.:  778 – 788

Chapter 85. A new insight into molybdate/boehmite interaction

pp.:  788 – 798

Chapter 86. Controlled coating of high surface area silica with titania overlayers by atomic layer deposition

pp.:  798 – 808

Chapter 87. Concept of the synthesis of novel platinum catalysts for selective hydrogenation of unsaturated carbonyl compounds

pp.:  808 – 816

Chapter 88. Storage and supply of hydrogen mediated by iron oxide: modification of iron oxides

pp.:  816 – 824

Chapter 89. Catalytic activity of bulk and supported sulfated zirconia

pp.:  824 – 834

Chapter 90. New one-step synthesis of superacid sulfated zirconia

pp.:  834 – 844

Chapter 91. Elaboration and characterization of a realistic Phillips model catalyst for ethylene polymerisation

pp.:  844 – 858

Chapter 92. Preparation of new basic mesoporous silica catalysts by ammonia grafting

pp.:  858 – 866

Chapter 93. Titania-silica catalysts prepared by sol-gel method for photoepoxidation of propene with molecular oxygen

pp.:  866 – 876

Chapter 94. Preparation of large surface area MnOx–ZrO2 for sorptive NOx removal

pp.:  876 – 884

Chapter 95. Preparation of CuOx–TiO2 nano-composite photocatalysts from intercalated layer structure

pp.:  884 – 894

Chapter 96. Vanadia-doped titanium pillared clay: preparation, characterization and SCR activity of NO by ammonia

pp.:  894 – 902

Chapter 97. Advanced preparation by sol–gel method of the encapsulated Pd/Al2O3 catalysts for methane combustion

pp.:  902 – 912

Chapter 98. Non-ionic surfactant templated synthesis of mesoporous silica in the presence of platinum salts

pp.:  912 – 920

Chapter 99. Synthesis and acid–base properties of catalysts based on magnesium and sodium-magnesium mixed phosphates

pp.:  920 – 928

Chapter 100. Preparation of Pd–Ce/ZrO2 catalysts for methane oxidation

pp.:  928 – 936

Chapter 101. The effect of cerium introduction on vanadium-USY catalysts

pp.:  936 – 946

Chapter 102. Rh–Co mordenite catalysts for the selective reduction of NO by methane

pp.:  946 – 954

Chapter 103. Surface characterization of WO3-TiO2/Al2O3 catalysts and reactivity on selective catalytic reaction of NO by NH3

pp.:  954 – 962

Chapter 104. Catalytic materials for the synthesis of hydrofluorocarbons

pp.:  962 – 974

Chapter 105. Preparation, characterization and reactivity in m-cresol methylation of new heterogeneous materials having basic properties

pp.:  974 – 984

Chapter 106. The effect of glycols in the organic preparation of V/P mixed oxide catalyst for the oxidation of n-butane to maleic anhydride

pp.:  984 – 996

Chapter 107. Synthesis and characterization of nanostructured MO2C on carbon material by carbothermal hydrogen reduction

pp.:  996 – 1004

Chapter 108. Carbon composite-based catalysts: new perspectives for the low-temperature H2S removal

pp.:  1004 – 1014

Chapter 109. Active carbon surface oxidation to optimize the support functionality and metallic dispersion of a Pd/C catalyst

pp.:  1014 – 1024

Chapter 110. n-Butane isomerization over Al-promoted sulfated zirconias. Influence of the sulfate content

pp.:  1024 – 1032

Chapter 111. Influence of preparation procedure on physical and catalytic properties of carbon-supported Pd-Au catalysts

pp.:  1032 – 1040

Chapter 112. Preparation of mesoporous highly dispersed Pd–Pt catalysts for deep hydrodesulfurization

pp.:  1040 – 1048

Chapter 113. Preparation of highly ordered CMI-1 and wormhole-like DWM mesoporous silica catalyst supports using C16(EO)10 as surfactant

pp.:  1048 – 1056

Chapter 114. Synthesis and characteriation of nanostructured mesoporous zirconia catalyst supports using non-ionic surfactants as templating agents

pp.:  1056 – 1066

Chapter 115. Effect of preparation parameters on the catalytic activities of sulfated ZrO2–SiO2 catalysts obtained by sol-gel process

pp.:  1066 – 1074

Chapter 116. Non-aggressive way for preparation of zirconium sulfate pillared clay using zirconium acetate developing high sulfur thermal stability over 830C

pp.:  1074 – 1084

Chapter 117. Influence of the preparation conditions on the structure of the active phase and catalytic properties of Ni-Co-molybdate propane oxydehydrogenation catalysts

pp.:  1084 – 1094

Chapter 118. Oxidized diamond as a new catalyst support

pp.:  1094 – 1102

Chapter 119. Preparation of catalytic membranes, micro-capsules and fabrics active in immobilized Fenton chemistry

pp.:  1102 – 1110

Chapter 120. Preparation of vanadium-based catalysts for selective catalytic reduction of nitrogen oxides using titania supports chemically modified with organosilanes

pp.:  1110 – 1118

Chapter 121. Design, preparation and testing of effective FeOx/SiO2 catalysts in methane to formaldehyde selective oxidation

pp.:  1118 – 1128

Chapter 122. New Fe–Mo–Ti mixed oxides prepared via the sol–gel method: comparison of the textural properties with solids obtained by impregnation

pp.:  1128 – 1136

Index

pp.:  1136 – 1142

Studies in Surface Science and Catalysis

pp.:  1142 – 1151

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