Olefin Metathesis and Metathesis Polymerization ( 2 )

Publication series :2

Author: Ivin   K. J.;Mol   J. C.  

Publisher: Elsevier Science‎

Publication year: 1997

E-ISBN: 9780080537979

P-ISBN(Paperback): 9780123770455

P-ISBN(Hardback):  9780123770455

Subject: O623.121 ethylene hydrocarbons

Language: ENG

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Description

This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis.

Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering.

  • Discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst
  • Considers commercial processes with examples from existing and new technologies
  • Provides a complete overview of the subject from its beginning to the present day

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Contents

pp.:  6 – 14

Preface

pp.:  14 – 16

Abbreviations

pp.:  16 – 18

Chapter 1. Introduction

pp.:  18 – 29

Chapter 2. Survey of catalyst systems

pp.:  29 – 67

Chapter 3. The metal carbene/metallacyclobutane mechanism

pp.:  67 – 99

Chapter 4. Related reactions

pp.:  99 – 109

Chapter 5. Ethene and terminal alkenes

pp.:  109 – 133

Chapter 6. Acyclic disubstituted and trisubstituted ethenes

pp.:  133 – 151

Chapter 7. Acyclic functionalized alkenes

pp.:  151 – 165

Chapter 8. Acyclic dienes

pp.:  165 – 188

Chapter 9. Cross-metathesis between acyclic compounds

pp.:  188 – 207

Chapter 10. Acetylenes

pp.:  207 – 241

Chapter 11. Ring-opening metathesis polymerization: general aspects

pp.:  241 – 277

Chapter 12. Monocyclic alkenes and polyenes

pp.:  277 – 305

Chapter 13. Polycyclic alkenes

pp.:  305 – 357

Chapter 14. Copolymers of cycloalkenes

pp.:  357 – 375

Chapter 15. Cross-metathesis between cyclic and acyclic olefins

pp.:  375 – 392

Chapter 16. Degradation of unsaturated polymers by metathesis

pp.:  392 – 414

Chapter 17. Applications of the olefin metathesis reaction

pp.:  414 – 428

Bibliography

pp.:  428 – 478

Index

pp.:  478 – 490

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