Description
The original properties of mesoporous molecular sieves are so unique that the design of most existing catalysts could be reconsidered. It might indeed be of interest to introduce MMS either as a support or as the active phase, merely on the basis of their high surface areas, narrow pore size distribution and flexibility in composition. The recent literature provides examples of MMS based catalysts of many types such as acid-base solids, supported metals and supported oxides, mixed oxides, anchored complexes and clusters, grafted organic functional groups and others. Examples of all these developments are documented in the present proceedings including some spectacular new proposals. The new metallic (Pt) mesophases are specially worth mentioning because they represent a new approach to producing non-supported highly dispersed metals.
In these proceedings the reader will find feature articles and regular papers from many worldwide groups, covering all aspects of synthesis, physical characterization and catalytic reactivity of MMS and their chemically modified forms. It is actually remarkable that this recent development brought together an even broader spectrum of scientists from traditionally unrelated fields such as those of liquid crystals, surfactants, sol-gels, amorphous oxides and mixed oxides, solid state, adsorbents and heterogeneous catalysts. Obviously, this is a fast-growing research area which triggers the imagination and creativity at the cross-road between mate
Chapter
Chapter 3. Catalytic properties of mesoporous molecular sieves prepared by neutral surfactant assembly
pp.:
40 – 54
Chapter 4. Structure simulation of mesoporous molecular sieves
pp.:
54 – 62
Chapter 5. In-situ XRD study of the initial stages of formation of MCM-41 in a tubular reactor
pp.:
62 – 70
Chapter 6. Internal modification of ordered mesoporous hosts
pp.:
70 – 82
Chapter 7. Mesoporous materials derived from layered silicates and the adsorption properties
pp.:
82 – 94
Chapter 8. Adsorption characterization of mesoporous molecular sieves
pp.:
94 – 102
Chapter 9. Synthesis and applications of nanoporous materials
pp.:
102 – 106
Chapter 10. The preparation of mesoporous metals from preformed surfactant assemblies
pp.:
106 – 112
Chapter 11. Preparation of novel mixed [Cu, Zn, Al] hexagonal and lamellar mesophases
pp.:
112 – 120
Chapter 12. Tubular aluminophosphate mesoporous materials containing framework silicon, vanadium and manganese
pp.:
120 – 128
Chapter 13. Mesoporous molecular sieve thin films
pp.:
128 – 136
Chapter 14. Nucleation, growth and form of mesoporous silica: role of defects and a language of shape
pp.:
136 – 146
Chapter 15. Structure and dynamic properties of surfactant systems
pp.:
146 – 152
Chapter 16. Silazane-silylation of mesoporous silicates: towards tailor-made support materials
pp.:
152 – 160
Chapter 17. Stabilization of M41S materials by trimethylsilylation
pp.:
160 – 168
Chapter 18. Improvement of structural integrity of mesoporous molecular sieves for practical applications
pp.:
168 – 176
Chapter 19. Transition metal-modified mesoporous silicas as catalysts for oxidation reactions
pp.:
176 – 188
Chapter 20. New organic chemical conversions over MCM-41-type materials
pp.:
188 – 200
Chapter 21. Sulfonic acid bearing mesoporous materials as catalysts in furan and polyol derivatization
pp.:
200 – 208
Chapter 22. Titanium containing MCM-41 molecular sieves prepared by secondary treatment
pp.:
208 – 218
Chapter 23. Possibilities of mesoporous materials in catalysis
pp.:
218 – 240
Chapter 24. Synthesis and characterization of MCM-41 with different pore size and Si/Al-ratio
pp.:
240 – 248
Chapter 25. Improved synthesis of MSU-X silica prepared by polyethylene oxide surfactants
pp.:
248 – 254
Chapter 26. Thermal decomposition of surfactant occluded in mesoporous MCM-41 type solids
pp.:
254 – 260
Chapter 27. Hybrid inorganic-organic mesoporous molecular sieves
pp.:
260 – 266
Chapter 28. Synthesis and characterization of aluminum-containing MCM-48
pp.:
266 – 274
Chapter 29. Preparation of highly ordered MCM-41 with docosyltrimethylammonium chloride (C22TMAC1) as a template and fine control of its pore size
pp.:
274 – 282
Chapter 30. Photoluminescence spectroscopic monitoring in the synthesis of mesoporous materials by microwave-induced heating
pp.:
282 – 290
Chapter 31.Effect of hydrothermal conditions on the synthesis of siliceous MCM-48 in mixed cationic-anionic surfactants systems
pp.:
290 – 298
Chapter 32. Templating effects in the synthesis of MCM-41/MCM-48 phases
pp.:
298 – 308
Chapter 33. Effect of A1 sources on the synthesis and acidic characteristics of mesoporous aluminosilicates of MCM-41 type
pp.:
308 – 318
Chapter 34. NMR relaxation and self-diffusion measurements on small molecules in MCM-41 with different pore size
pp.:
318 – 326
Chapter 35. Structural properties of simple sorbed gases (N2, Kr, D20) confined in MCM-41 sample (Ø = 40 Å)
pp.:
326 – 334
Chapter 36. FT-IR spectroscopic studies of the acidic properties of mesoporous molecular sieves by adsorbed carbon monoxide
pp.:
334 – 342
Chapter 37. Adsorption methods for characterization of surface and structural properties of mesoporous molecular sieves
pp.:
342 – 350
Chapter 38. The creation of MOx surface species on pure silica MCM-48 using gas- and liquid-phase modifications with M-acetylacetonate complexes
pp.:
350 – 360
Chapter 39. Surface properties of Cu2O/MCM-41 mesoporous systems
pp.:
360 – 368
Chapter 40. Promoter (PO43-) assisted efficient synthesis of all silica, alumino-silicate and titanium-silicate analogues of MCM-41 type mesoporous materials
pp.:
368 – 374
Chapter 41. Coordinative anchoring of zinc phthalocyanine in Ti-MCM-41
pp.:
374 – 382
Chapter 42. Synthesis and characterization of metal incorporated H1 SiO2 materials
pp.:
382 – 390
Chapter 43. Mesoporous molecular sieve immobilized enzymes
pp.:
390 – 398
Chapter 44. Structure modification of MCM-41, HMS and MSU-X mesoporous silicates by ex-situ post-synthesis hydrothermal treatment
pp.:
398 – 408
Chapter 45. Ordered mesoporous materials as catalyst supports
pp.:
408 – 416
Chapter 46. Influence of alkali ion concentration on pore size distribution and vanadium content of [V]-MCM-41
pp.:
416 – 422
Chapter 47. EPR and UV-visible fluorescence spectroscopic evidences for intermediate phases during the formation of micelle-templated silicas
pp.:
422 – 430
Chapter 48. Meerwein-Ponndorf-Verley reductions mediated by lanthanide-alkoxide-functionalized mesoporous silicates
pp.:
430 – 438
Chapter 49. Diels-Alder reaction of isoprene with different dienophiles catalyzed by zeolites and MCM-41
pp.:
438 – 446
Chapter 50. Dehydrogenation reactions on MCM-41
pp.:
446 – 454
Chapter 51. Catalytic properties of MCM-41 for the feedstock recycling of plastic and lubricating oil wastes
pp.:
454 – 462
Chapter 52. Guanidine linked to micelle-templated mesoporous silicates as base catalyst for transesterification
pp.:
462 – 470
Chapter 53. Probing the active sites of aluminated mesoporous molecular sieve MCM-41 by secondary synthesis in the conversion of cyclohexanol
pp.:
470 – 478
Chapter 54. Fe-containing mesoporous molecular sieves as benzylation catalysts
pp.:
478 – 486
Chapter 55. Oxidation of cholesterol over mesoporous MCM-41 materials
pp.:
486 – 494
Chapter 56. Alumoxo-MCM-41 as host in the Co-oligomerization of ethene and propene with Et(Ind)2Zr(CH3)2
pp.:
494 – 502
Chapter 57. Hydrodemetallization of nickel tetraphenylporphyrin over Mo catalysts supported on mesoporous molecular sieves
pp.:
502 – 510
Chapter 58. New Mo and NiMo catalysts supported on MCM-41/Alumina for thiophene hydrodesulfurization
pp.:
510 – 518
Chapter 59. Diastereoselective hydrogenation of some prostaglandins intermediates and compounds over MCM-41 supported Ru
pp.:
518 – 526
Chapter 60. Synthesis and transformation of thiols and organic sulfides on MCM-4 1 mesoporous molecular sieves
pp.:
526 – 534
Chapter 61. Synthesis strategies leading to pure alumina mesophases in aqueous solution
pp.:
534 – 536
Chapter 62. Influence of pH adjustment on structure, stability, and catalytic activity of Al-MCM-41 mesoporous molecular sieves
pp.:
536 – 544
Chapter 63. Improvement of the thermal stability of mesostructured metal oxides with zirconia as the example
pp.:
544 – 552
Chapter 64. EPR studies of the formation mechanism of the mesoporous materials MCM-41
pp.:
552 – 560
Chapter 65. Variable temperature 129Xe NMR studies of xenon adsorbed on mesoporous MCM-41 molecular sieves
pp.:
560 – 568
Chapter 66. Photochemical properties of rhodamine-B dye molecules included within mesoporous molecular sieves
pp.:
568 – 576
Chapter 67. Fe and Co modifications of siliceous MCM-41 and 48 using direct or post-synthesis methods
pp.:
576 – 584
Chapter 68. EXAFS multiple scattering characterization of metal modified mesoporous sieves
pp.:
584 – 592
Chapter 69. Hysteresis in physical sorption for MCM
pp.:
592 – 600
Chapter 70. Determination of the MCM-41 (25 Å and 40 Å) wall mean densities from sorption capacity and neutron diffraction measurements
pp.:
600 – 608
Chapter 71. Shape selectivity of mesoporous aluminosilicates in the transformation of benzenic hydrocarbons
pp.:
608 – 616
Author Index
pp.:
616 – 620
Subject Index
pp.:
620 – 626
Studies in Surface Science and Catalysis
pp.:
626 – 634