Heterogeneous Catalysis in Organic Chemistry

Author: Smith   Gerard V.;Notheisz   Ferenc  

Publisher: Elsevier Science‎

Publication year: 1999

E-ISBN: 9780080524801

P-ISBN(Paperback): 9780126516456

P-ISBN(Hardback):  9780126516456

Subject: O621.25 chemistry, organic chemistry reaction

Language: ENG

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Description

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses.

Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry.

Many academic organic chemists are not aware of recent advances in heterogeneous

Chapter

Front Cover

pp.:  1 – 4

Contents

pp.:  8 – 14

Preface

pp.:  14 – 18

Chapter 2. Hydrogenations

pp.:  46 – 114

Chapter 3. Enantioselective Hydrogenations

pp.:  114 – 136

Chapter 4. Hydrogenolysis

pp.:  136 – 236

Chapter 5. Bond Breaking Reactions

pp.:  236 – 246

Chapter 6. Oxidations

pp.:  246 – 264

Chapter 7. Immobilized Homogeneous Catalysts

pp.:  264 – 308

Appendix

pp.:  308 – 312

Author Index

pp.:  312 – 346

Subject Index

pp.:  346 – 364

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