Aqueous Systems at Elevated Temperatures and Pressures :Physical Chemistry in Water, Steam and Hydrothermal Solutions

Publication subTitle :Physical Chemistry in Water, Steam and Hydrothermal Solutions

Author: Fernandez-Prini   Roberto;Harvey   A. H.;Palmer   D. A.  

Publisher: Elsevier Science‎

Publication year: 2004

E-ISBN: 9780080471990

P-ISBN(Paperback): 9780125444613

P-ISBN(Hardback):  9780125444613

Subject:

Language: ENG

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Description

The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors’ goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem.


The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form.


To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties)

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 12

Preface

pp.:  6 – 8

Foreword

pp.:  8 – 14

Contents

pp.:  12 – 6

Chapter 2. Near-critical behavior of aqueous systems

pp.:  42 – 86

Chapter 3. Aqueous solubility of volatile nonelectrolytes

pp.:  86 – 112

Chapter 4. Calculation of standard thermodynamic properties of aqueous electrolytes and nonelectrolytes

pp.:  112 – 162

Chapter 5. Hydrothermal solution structure: experiments and computer simulations

pp.:  162 – 196

Chapter 6. Vapor—liquid equilibrium involving aqueous, binary nonelectrolytes

pp.:  196 – 218

Chapter 7. Binary homogeneous nucleation in selected aqueous vapor mixtures

pp.:  218 – 256

Chapter 8. Solute concentration effects on reaction thermodynamics in steam cycle fluids

pp.:  256 – 290

Chapter 9. Stable isotope partitioning in aqueous and hydrothermal systems to elevated temperatures

pp.:  290 – 334

Chapter 10. Transport properties in high temperature and pressure ionic solutions

pp.:  334 – 390

Chapter 11. Electrochemical processes in high-temperature aqueous solutions

pp.:  390 – 422

Chapter 12. Partitioning of electrolytes to steam and their solubilities in steam

pp.:  422 – 454

Chapter 13. Ionization equilibria of acids and bases under hydrothermal conditions

pp.:  454 – 506

Chapter 14. Solubility and surface adsorption characteristics of metal oxides

pp.:  506 – 610

Chapter 15. Phase equilibria of water—salt systems at high temperatures and pressures

pp.:  610 – 656

Chapter 16. Kinetics and mechanisms of hydrothermal organic reactions

pp.:  656 – 690

Chapter 17. Water chemistry in commercial water—steam cycles

pp.:  690 – 730

Chapter 18. Hydrothermal synthesis of ceramic materials

pp.:  730 – 758

Index

pp.:  758 – 768

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