

Author: Moskovits M. Ozin G. A.
Publisher: Society for Applied Spectroscopy
ISSN: 0003-7028
Source: Applied Spectroscopy, Vol.26, Iss.4, 1972-07, pp. : 481-481
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Abstract
The low temperature matrix isolation technique for producing and examining reactive or otherwise unstable species has been developed to a high degree of sophistication in the past 20 years. Often, the desired molecular fragment is generated by cocondensing a gaseous mixture, for example, CO in Ar, with a molecule or atom generated at high temperature by evaporation from a hot filament or by effusion from a Knudsen cell, for example, Pd or Pt atoms. Using this method the previously unknown carbonyls of Pd and Pt were generated and identified by matrix isolation infrared spectroscopy.
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