Synthesis and spectroscopic properties of (C2F x Br0.01 · yCH3CN) n (0.5 < x < 1.0) intercalation compounds

Author： Pinakov D.   Sheludyakova L.   Chekhova G.   Alferova N.   Mazalov L.   Gevko P.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 0020-1685

Source： Inorganic Materials, Vol.46, Iss.11, 2010-11, pp. : 1186-1191

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Abstract

(C2F x Br0.01 · yCH3CN) n intercalation compounds, with (C2F x Br0.01) n (0.5 < x < 1.0) as a host and CH3CN as a guest (x and y are stoichiometric coefficients), have been synthesized. The influence of fluorine content on the spectroscopic characteristics of the intercalation compounds with acetonitrile has been studied by Raman, IR, and X-ray photoelectron spectroscopies. The macroscopic properties of the intercalation compounds are shown to correlate with their spectroscopic characteristics. The data for the compounds stored in air for about a year indicate that their surface and interior differ in structure.

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