Accounting for the Adsorption of Anions When Interpreting the Mechanism of Electrodeposition of Metals from Complex Electrolytes: The Reaction Order by the Electrochemically Active Ion

Author： Rogozhnikov N.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1023-1935

Source： Russian Journal of Electrochemistry, Vol.41, Iss.7, 2005-07, pp. : 725-730

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Abstract

The relationship between the current and the bulk concentration of complex ions during concurrent specific adsorption of an electrochemically active complex ion and a complexing ligand is considered. The effect of parameters that characterize adsorption of such ions and the structure of the electrical double layer on this relationship is analyzed.

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