Functional self-assembly of hydrogen-bonded 3D coordination networks constructed from 1,2,4,5-benzenetetracarboxylic acid

Author： Bo Q.   Zhao S.   Zhang Z.   Sheng Y.   Sun Z.   Sun G.   Chen C.   Li Y.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3284

Source： Russian Journal of Coordination Chemistry, Vol.33, Iss.7, 2007-07, pp. : 471-481

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Hydrothermal synthesis, characterization (IR, TG/DTA, element analysis, inductively coupled plasma (ICP)) and single-crystal X-ray structures of H4Btec hydrate and its two cobalt complexes, colorless [H4Btec · 2H2O] n (I), pink [Co(H2O)6(H2Btec)] n (II), and nacarat {[Co(H2O)3(H2Btec)(Phen)] · H2O} n (III) (H4Btec = 1,2,4,5-benzenetetracarboxylic acid, Phen = 1,10-phenanthroline) have been solved. The results showed that I forms a 3D O-H…O hydrogen-bonded network generated from H4Btec and water molecules, II presents a 3D network constructed by mononuclear [Co(H2O)6]2+ cations and H2Btec2− dianions through extensive hydrogen-bonding interactions, and III gives rise to a pseudo-octahedral coordination geometry. Extensive hydrogen-bonding interactions have significant effects in configuring a 3D network constructed by mononuclear [Co(H2Btec)(Phen)(H2O)3] neutral molecules and a water molecules.

Related content

Synthesis and characterization of two 3-D polymeric lanthanide complexes constructed from 1,2,4,5-benzenetetracarboxylic acid

By Li Xiaohu   Wang Yanping   Ma Zhiyun   Zhang Ronglan   Zhao Jianshe  

Journal of Coordination Chemistry, Vol. 63, Iss. 6, 2010-03 ,pp. : 1029-1037 (9)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Self-Assembly of a 1D Hydrogen-Bonded Polymer from a Hexamethyltetraaza Macrocyclic Nickel(II) Complex and Isophthalic Acid

By Lim In-Taek   Choi Ki-Young  

Molecules, Vol. 18, Iss. 6, 2013-06 ,pp. : 6608-6619 (12)

MDPI

Access to resources Recommend Favorite

Synthesis and characterization of metal polycarboxylates constructed from lanthanides(iii) and 1,2,4,5-benzenetetracarboxylic acid

By Rzączyńska Z.   Ostasz A.   Sikorska-Iwan M.   Głuchowska H.   Olszewska E.   Pikus S.  

Journal of Thermal Analysis and Calorimetry, Vol. 84, Iss. 3, 2006-05 ,pp. : 575-579 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Open-framework coordination complexes from hydrogen-bonded networks: toward host/guest complexes

By Beatty A.M.  

Coordination Chemistry Reviews, Vol. 246, Iss. 1, 2003-11 ,pp. : 131-143 (13)

Elsevier

Access to resources Recommend Favorite

A hydrogen-bonded 3D coordination network in a complex of Cu(II) nitrate with 1,2,4-triazole-5-one and 1,10-phenanthroline

By Li Na   Chen Sanping   Gao Shengli  

Journal of Coordination Chemistry, Vol. 60, Iss. 2, 2007-01 ,pp. : 117-123 (7)

Taylor & Francis Ltd

Access to resources Recommend Favorite