Copper(II) complex with thienyltrifluoroacetylacetone and dimethyl sulfoxide: Synthesis and crystal structure

Author： Magerramov A.   Alieva R.   Bakhmanova F.   Sulhnejat R.   Chyragov F.   Askerov R.   Potekhin K.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3284

Source： Russian Journal of Coordination Chemistry, Vol.37, Iss.1, 2011-01, pp. : 45-47

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

A new copper(II) complex with thienyltrifluoroacetone (Tfa) and dimethyl sulfoxide (DMSO), Cu(Tfa)2DMSO, was synthesized, and its X-ray diffraction analysis was carried out. The crystals were triclinic: a = 9.4496(5), b = 10.5075(6), c = 11.9160(6) Å, α = 82.600(1)°, β = 84.116(1)°, γ = 77.904(1)°, V = 1143.8(1) Å3, space group P , Z = 2, ρcalcd = 1.696 mg/m3, R = 0.0700. The environment of the copper atom was formed by four oxygen atoms of two thienyltrifluoroacetylacetone molecules and one oxygen atom of DMSO.

Related content

Synthesis, Crystal Structure, and Cytotoxicity of a Copper(II) Complex With Matrine

By Mao Li   Gu Yun-Qiong   Liu Yan-Cheng   Chen Zhen-Feng   Liang Hong  

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 44, Iss. 1, 2014-01 ,pp. : 43-47 (5)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Synthesis, characterization and crystal structure of a novel binuclear copper(II) complex

By Sao Yun   Chen Ya-Guang   Zhu Dong-Sheng   Liu Qun  

Journal of Coordination Chemistry, Vol. 59, Iss. 5, 2006-03 ,pp. : 537-544 (8)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Synthesis and Structure of the Copper(II) Nitrate Complex with 1-(3-Methyl-1-phenylpyrazol-5-onylidene-4)-3,3-dimethyl-1,2,3,4-tetrahydroisoquinoline

By Sokol V.   Davydov V.   Merkur'eva N.   Sergienko V.   Al-Saleh O.   Shklyaev Yu.  

Russian Journal of Coordination Chemistry, Vol. 31, Iss. 11, 2005-11 ,pp. : 780-789 (10)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite

Synthesis, Crystal Structure and Characterization of Polynuclear Potassium(I), Copper(II) and Cobalt(II) Complex with Acetylacetonethylenediamine

By Shen Liang   Sheng Guoding   Qiu Jin   Zhang Yijian  

Journal of Coordination Chemistry, Vol. 56, Iss. 7, 2003-01 ,pp. : 603-610 (8)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Synthesis, Crystal Structure and Bovine Serum Albumin Interaction Studies of a Binuclear Copper(II) Complex with Naphthylacetic Acid

By Liu Yu-Fen   Xu Xing-You   Xia Hai-Tao   Wang Da-Qi   Liu Hui  

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 39, Iss. 7, 2009-09 ,pp. : 400-405 (6)

Taylor & Francis Ltd

Access to resources Recommend Favorite