Author： Zakoshansky V.
Publisher： MAIK Nauka/Interperiodica
ISSN： 1070-3632
Source： Russian Journal of General Chemistry, Vol.81, Iss.5, 2011-05, pp. : 845-864
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Abstract
This article presents direct evidence of the occurrence of cumene oxidation resulting from the presence of gaseous oxygen (O 2gas ) at the gas-liquid interface, demonstrating a markedly higher magnitude of process selectivity, as compared to oxidation that is promoted by dissolved oxygen ( 2liquid ). The significant contribution of O 2gas to the formation of cumene hydroperoxide under bubble-type process conditions is also discussed, emphasizing that the hydroperoxide formation rate is composed of two components:
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Russian Journal of General Chemistry, Vol. 81, Iss. 5, 2011-05 ,pp. :
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