Author： Salomatina O. Yarovaya O. Korchagina D. Gatilov Yu. Polovinka M. Barkhash V.
Publisher： MAIK Nauka/Interperiodica
ISSN： 1070-4280
Source： Russian Journal of Organic Chemistry, Vol.41, Iss.9, 2005-09, pp. : 1280-1285
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Abstract
Transformations of isocaryophyllene diepoxide (an isomer of widely spread natural sesquiterpene) were studied in various acidic media under conditions of homogeneous and heterogeneous catalysis. A number of previously unknown compounds were thus obtained. The experimental data were compared with the results of molecular-mechanics and quantum-chemical simulation of the most probable transformation paths.
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