Author： Dneprovskii A. Kasatochkin A. Boyarskii V. Ermoshkin A. Yakovlev A.
Publisher： MAIK Nauka/Interperiodica
ISSN： 1070-4280
Source： Russian Journal of Organic Chemistry, Vol.42, Iss.8, 2006-08, pp. : 1120-1130
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
In the free-radical addition of a number of organohalogen reagents to cyclic alkenes and dienes in the presence of copper(I) halides the composition of the reaction products is governed by the stage of a fast halogen transfer from the copper derivative to the alkyl radical. Under these conditions in contrast to the free-radical addition reactions initiated by UV light or peroxide initiators the intramolecular rearrangements are suppressed, the stereoselectivity of the reaction changes, and also some adducts contain halogen atoms different from those present in the organohalogen reagent employed.
Related content
Access to resources
Recommend
Free-Radical Reaction Routes in γ-Irradiated β-D-Fructose
By Abagyan G. V. Apresyan A. S.
High Energy Chemistry, Vol. 38, Iss. 6, 2004-11 ,pp. :
By Wan Danyang Yang Yudong Liu Xingyan Li Mingliang Zhao Siling You Jingsong
European Journal of Organic Chemistry, Vol. 2016, Iss. 1, 2016-01 ,pp. :