Separation of racemic salycylaldehydes containing isobornyl substituent using (R)-1-phenylethylamine

Author： Buravlev E.   Chukicheva I.   Dolgushin F.   Kuchin A.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-4280

Source： Russian Journal of Organic Chemistry, Vol.46, Iss.5, 2010-05, pp. : 649-654

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Racemic salicylaldehydes containing isobornyl substituent were separated by their conversion into diastereomers by the reaction with (R)-1-phenylethylamine. The absolute configuration of the intermediate Schiff bases and separated aldehyde eneatiomers was established by XRD analysis.

Related content

(R)-1-Phenylethylamine as chiral auxiliary in the diastereoselective synthesis of tetrahydro-β-carboline derivatives

By Siwicka Aleksandra   Wojtasiewicz Krystyna   Leniewski Andrzej   Maurin Jan K   Zawadzka Anna   Czarnocki Zbigniew  

Canadian Journal of Chemistry, Vol. 85, Iss. 12, 2007-12 ,pp. : 1033-1036 (4)

NRC Research Press

Access to resources Recommend Favorite

Simple Resolution of Racemic Salicylic Aldehydes Having an Isobornyl Substituent

By Buravlev Evgeny   Chukicheva Irina   Kutchin Aleksandr  

Synthetic Communications, Vol. 39, Iss. 20, 2009-01 ,pp. : 3639-3646 (8)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Uncommon transformations of methyl (1S,2S,3R,4R)-2,3-isopropylidenedioxy-5-iodomethyl-2-tetrahydrofurylacetate initiated by bases

By Ivanova N.   Valiullina Z.   Shitikova O.   Miftakhov M.  

Russian Journal of Organic Chemistry, Vol. 42, Iss. 11, 2006-11 ,pp. : 1701-1705 (5)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite

d(1R,2S,5R)-Menthyl Phosphinate and Its Properties

By Kolodyazhnyi O.  

Russian Journal of General Chemistry, Vol. 75, Iss. 4, 2005-04 ,pp. : 656-657 (2)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite

Specificity of the reaction of (−)-1-{(1S,2R,4R)-1-ethenyl-2-hydroxy-7,7-dimethylbicyclo[2.2.1]hept-2-yl}xethanone with ethenylmagnesium bromide

By Vostrikov N.   Vasikov V.   Miftakhov M.  

Russian Journal of Organic Chemistry, Vol. 42, Iss. 7, 2006-07 ,pp. : 962-965 (4)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite