The Reactions of 6-(tert-Butyl)-3-hydrazino-1,2,4-triazin-5(2H)-one with Carbonyl Compounds

Author： Mironovich L. M.   Ivanov M. A.  

Publisher： Springer Publishing Company

ISSN： 0009-3122

Source： Chemistry of Heterocyclic Compounds, Vol.39, Iss.9, 2003-09, pp. : 1207-1209

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Abstract

The reaction of 6-(tert-butyl)-3-hydrazino-1,2,4-triazin-5(2H)-one with acetone and benzaldehyde yields the corresponding hydrazones. In the presence of thionyl chloride the benzaldehyde hydrazone is converted to 3-(tert-butyl)-6-phenyl-1,2,4-triazolo[4,3-b]-1,2,4-triazin-2(1H)-one and this can also be formed via the acylation of the starting hydrazinotriazinone using benzoyl chloride.

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