Heterocyclic Derivatives of Fullerene C60. 2. Cycloaddition to Fullerene C60 of the Products of Dehydrochlorination of N-Benzyltrifluoroacetimidoyl Chlorides

Author: Reinov M. V.   Yurovskaya M. A.   Streletskiy A. V.   Boltalina O. V.  

Publisher: Springer Publishing Company

ISSN: 0009-3122

Source: Chemistry of Heterocyclic Compounds, Vol.40, Iss.9, 2004-09, pp. : 1150-1154

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Abstract

It has been shown that, depending on the structure, the products of dehydrochlorination of N-benzyltrifluoroacetimidoyl chlorides react with C60 under the action of triethylamine as a [3 + 2] cycloaddition (with the formation of fulleropyrrolines) or a [4 + 2] cycloaddition (with the formation of fulleropiperideines).