Author: Nedolya N. Tarasova O. Albanov A. Klyba L. Trofimov B.
Publisher: Springer Publishing Company
ISSN: 0009-3122
Source: Chemistry of Heterocyclic Compounds, Vol.46, Iss.1, 2010-05, pp. : 61-65
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
Using as example 3-methoxy-1-(2-methoxyethyl)-2-methylsulfanylpyrrole, obtained in one preparative stage from α-lithiated methoxyallene and 2-methoxyethyl isothiocyanate, a facile cleavage of a C–O bond in the N-(2-methoxyethyl) substituent by the t-BuOK–DMSO system has been discovered, opening access to a new class of N-vinylpyrroles (through β-elimination of methanol).
Related content
By Toumi B. Samarat A. Harizi A. Amri H.
Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 185, Iss. 3, 2010-03 ,pp. :
Liquid phase methanol and dimethyl ether synthesis from syngas
Topics in Catalysis, Vol. 32, Iss. 3-4, 2005-03 ,pp. :
By Klyba L. Nedolya N. Shlyakhtina N. Zhanchipova E.
Russian Journal of Organic Chemistry, Vol. 41, Iss. 10, 2005-10 ,pp. :