Author： Mazalov L. Trubina S. Fomin E. Oglezneva I. Parygina G. Bausk N. Igumenov I.
Publisher： Springer Publishing Company
ISSN： 0022-4766
Source： Journal of Structural Chemistry, Vol.45, Iss.5, 2004-09, pp. : 800-807
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Abstract
The Cu(acac)2 complex was investigated by X-ray emission and XANES spectroscopy using synchrotron radiation. Structural data for the complex were obtained in chloroform solution and C2F matrix. The experimental spectra and their fitting on a single scale of binding energies point to possible relaxation effects. As shown by model quantum-chemical calculations, the structure and energy position of the LUMOs constructed from the vacant metal 4
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