NMR structural aspects of the chemistry of V, Mo, W polyoxometalates

Author: Fedotov M.   Maksimovskaya R.  

Publisher: Springer Publishing Company

ISSN: 0022-4766

Source: Journal of Structural Chemistry, Vol.47, Iss.5, 2006-09, pp. : 952-978

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Abstract

The results of structural investigations of vanadium, molybdenum, and tungsten polyoxoanions (PA) by 17O, 51V, 95Mo, 183W, and heteroatom NMR are generalized in this review. NMR spectroscopy possibilities to determine the structure of PA are discussed. NMR data on PA of different structures compositions nuclei are demonstrated.