An experimental evaluation of cleaning methods for fossil ostracod Mg/Ca and Sr/Ca determination

Author: Jin Zhangdong   Bickle Mike   Chapman Hazel   Yu Jimin   Greaves Mervyn   Wang Sumin   Chen Shiyue  

Publisher: Springer Publishing Company

ISSN: 0921-2728

Source: Journal of Paleolimnology, Vol.36, Iss.2, 2006-08, pp. : 211-218

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Abstract

To evaluate the effect of sample preparation on the trace element composition of ostracod shells, fossil shells subjected to various cleaning steps were analyzed by ICP-AES. The variations in ostracod Mg/Ca ratios reveal that fossil ostracod samples cleaned by ultrasonic methanol yield lower values than those by other methods, including increasingly rigorous reductive cleaning. In our sample sets, shell Mg/Ca decreases ∼ ∼1.5 mmol/mol during clay removal. Sample Sr/Ca results do not seem to vary significantly under the equivalent cleaning steps. For ostracod analysis, pre-treatment using multiple methanol ultrasonic cleaning is suggested to be used for gaining an appropriate result.