Author： Pirngruber Gerhard D. Roy Pijus K.
Publisher： Springer Publishing Company
ISSN： 1011-372X
Source： Catalysis Letters, Vol.93, Iss.1-2, 2004-03, pp. : 75-80
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
The mechanism of N2O decomposition over an 18O-labeled Fe-ZSM-5 catalyst was studied. The isotope distribution of the O2 produced during N2O decomposition was statistical. This shows that O2 was formed from a pool of equilibrated surface oxygen atoms. The size of the pool was 1.0 O/Fe, i.e. most or all of the iron clusters took part in the reaction. The reactivity of the oxygen atoms in the pool was low. They did not exchange with 18O2 to a significant extent.
Related content
Studies of N2O Adsorption and Decomposition on Fe–ZSM-5
By Wood B.R. Reimer J.A. Bell A.T.
Journal of Catalysis, Vol. 209, Iss. 1, 2002-07 ,pp. :
Access to resources
Recommend
