Phase Equilibria in Fe-Cu-X (X: Co, Cr, Si, V) Ternary Systems

Author： Wang Cui Ping   Liu Xing Jun   Ohnuma Ikuo   Kainuma Ryosuke   Ishida kiyohito  

Publisher： Springer Publishing Company

ISSN： 1054-9714

Source： Journal of Phase Equilibria, Vol.23, Iss.3, 2002-06, pp. : 236-245

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Abstract

Phase equilibria on the Fe-Cu side in the Fe-Cu-X (X: Co, Cr, Si, V) system were experimentally determined over the temperature range of 1073-1273 K. Based on the present results and previous works, the thermodynamic assessments of the phase equilibria in the Fe-Cu-X system were evaluated using the Calculation of Phase Diagram (CALPHAD) method. The Gibbs energies (G) of the bcc, fcc, and liquid phases are described by the subregular solution model, and a set of thermodynamic parameters enable us to calculate various isothermal and vertical sections and the miscibility gaps of the solid and liquid phases.

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