

Author: Grundy A. Hallstedt Bengt Gauckler Ludwig
Publisher: Springer Publishing Company
ISSN: 1054-9714
Source: Journal of Phase Equilibria, Vol.24, Iss.1, 2003-02, pp. : 21-39
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Abstract
Experimental data on the thermodynamics and the phase diagram of the Mn-O system were reviewed, and by application of the CALPHAD method, a consistent set of thermodynamic model parameters was optimized. The phases pyrolusite (MnO2), bixbyite (Mn2O3), and hausmannite (Mn3O4) were described as stoichiometric compounds. Manganosite (Mn1−
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