Reaction of α,β-unsaturated trifluoromethyl ketones with cyclic enamines

Author： Nenajdenko V. G.   Druzhinin S. V.   Balenkova E. S.  

Publisher： Springer Publishing Company

ISSN： 1066-5285

Source： Russian Chemical Bulletin, Vol.53, Iss.2, 2004-02, pp. : 435-442

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Abstract

The reactions of α,β-unsaturated trifluoromethyl ketones containing aromatic and heteroaromatic substituents with 1-morpholinocyclopentene, 1-morpholinocyclohexene, and 1-methyl-4-morpholino-1,2,5,6-tetrahydropyridine were studied. The reactions proceeded stereospecifically to give the corresponding bicyclo[3.2.1]octane, bicyclo[3.3.1]nonane, and azabicyclo[3.3.1]nonane derivatives.

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