Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br

Author： Sartori David   Hurst Stephanie   Wood Nathan   Larsen Raymond   Abbott Edwin  

Publisher： Springer Publishing Company

ISSN： 1074-1542

Source： Journal of Chemical Crystallography, Vol.35, Iss.12, 2005-12, pp. : 995-998

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space groupC2/C witha = 17.262(5) Å,b = 9.388(2) Å,C = 7.557(2) Å, β = 113.47(2)∘, andZ = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br2. The195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at −1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.

Related content

Na2PtF6, its Crystal Structure, Characterization, and Ammonolysis to [Na(NH3)3]2[PtF6]

By  

ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 2, 2015-02 ,pp. : 298-303 (6)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Synthesis and Crystal Structure of Charge-Transfer Salt (TTF)[Pt(mnt)2]

By Wang Shi   He Wenrui   Huang Wei  

Journal of Chemical Crystallography, Vol. 41, Iss. 3, 2011-03 ,pp. : 430-433 (4)

Springer Publishing Company

Access to resources Recommend Favorite

Crystal Structure and Chemical Bonding Analysis of BaPtCd2

By  

ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 3, 2015-03 ,pp. : 557-560 (4)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Crystal Structure and Chemical Bonding Analysis of BaPtCd2

By  

ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 3‐4, 2015-03 ,pp. : 557-560 (4)

John Wiley & Sons Inc

Access to resources Recommend Favorite

A 2D Network in Co-Crystal (1:1) Based on trans -[PtBr 2 (Acetoxime) 2 ] and 18-Crown-6

By Bulatov Evgeny  

Journal of Chemical Crystallography, Vol. 42, Iss. 4, 2012-04 ,pp. : 352-355 (4)

Springer Publishing Company

Access to resources Recommend Favorite