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Low Temperature Heat Capacity and Thermodynamic Functions of LiCoO₂

Author： Kawaji H. Takematsu M. Tojo T. Atake T. Hirano A. Kanno R.

Publisher： Springer Publishing Company

ISSN： 1388-6150

Source： Journal of Thermal Analysis and Calorimetry, Vol.68, Iss.3, 2002-06, pp. : 833-839

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

The sample of LiCoO₂ was synthesized, and the heat capacity was measured by adiabatic calorimetry between 13 and 300 K. The smoothed values of the heat capacity were calculated from the data. The thermodynamic functions, standard enthalpy, entropy and Gibbs energy, of LiCoO₂ were calculated from the heat capacity and the numerical values are tabulated at selected temperatures from 15 to 300 K. The heat capacity, enthalpy, entropy, and Gibbs energy at T=298.15 K are 71.57 J K⁻¹mol⁻¹, 9.853 kJ mol⁻¹, 52.45 J K⁻¹ mol⁻¹, −5.786 kJ mol⁻¹, respectively.

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